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Author(s):   Vedeneev, V.I.; Teitel'boim, M.A.; Shoikhet, A.A.
Title:   The photolysis of CF3I in the presence of O2 and Br2. 2. Determination of rate constants for the reactions of CF3 radicals with O2 and F2
Journal:   Bull. Acad. Sci. USSR Div. Chem. Sci. (Engl. Transl.)
Page(s):  
Year:   1979
Reference type:   Journal article
Squib:   1979VED/TEI2475

Reaction:   ·CF3 + O2CF3O2
Reaction order:   2
Reference reaction:   ·CF3 + Br2CF3Br + Br·
Reference reaction order:   2
Temperature:   253 - 343 K
Pressure:  2.67E-2 - 0.93 bar
Rate expression:   1.12±1.2x10-1 e2420 [±8314472 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Pressure measurement

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
253 3.54E0
275 3.23E0
300 2.95E0
325 2.74E0
343 2.62E0