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Accessibility information
Author(s):   Chang, J.S.; Kaufman, F.
Title:   Kinetics of the reactions of hydroxyl radicals with some halocarbons: CHFCl2, CHF2Cl, CH3CCl3, C2HCl3, and C2Cl4
Journal:   J. Chem. Phys.
Volume:   66
Year:   1977
Reference type:   Journal article
Squib:   1977CHA/KAU4989

Reaction:   CH3CCl3 + ·OHH2O + CCl3CH2
Reaction order:   2
Temperature:   275 - 405 K
Pressure:  2.93E-3 - 7.60E-3 bar
Rate expression:   1.94x10-12 [±2.32x10-13 cm3/molecule s] e-11058 [±332 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
275 1.54E-14
300 2.31E-14
325 3.24E-14
350 4.35E-14
375 5.60E-14
400 6.99E-14
405 7.28E-14