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Accessibility information
Author(s):   Clyne, M.A.A.; Holt, P.M.
Title:   Reaction Kinetics Involving Ground X2π and Excited A2Σ+ Hydroxyl Radicals. Part 1. - Quenching Kinetics of OH A2Σ+ and Rate Constants for Reactions of OH X2π with CH3CCl3 and CO
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   75
Year:   1979
Reference type:   Journal article
Squib:   1979CLY/HOL569

Reaction:   CH3CCl3 + ·OHH2O + CCl3CH2
Reaction order:   2
Temperature:   293 - 430 K
Pressure:  2.00E-3 - 2.60E-3 bar
Rate expression:   2.41x10-12 [cm3/molecule s] e-11557 [±931 J/mole]/RT
Uncertainty:   1.32000005
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
293 2.10E-14
300 2.34E-14
325 3.34E-14
350 4.54E-14
375 5.91E-14
400 7.45E-14
425 9.15E-14
430 9.50E-14