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Author(s):   Kurylo, M.J.; Anderson, P.C.; Klais, O.
Title:   A flash photolysis resonance fluorescence investigation of the reaction OH + CH3CCl3 →’ H2O + CH2CCl3
Journal:   Geophys. Res. Lett.
Volume:   6
Year:   1979
Reference type:   Journal article
Squib:   1979KUR/AND760

Reaction:   CH3CCl3 + ·OHH2O + CCl3CH2
Reaction order:   2
Temperature:   253 - 363 K
Pressure:  1.33E-2 bar
Rate expression:   5.4x10-12 [±1.83x10-12 cm3/molecule s] e-15049 [±906 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
253 4.22E-15
275 7.48E-15
300 1.29E-14
325 2.06E-14
350 3.06E-14
363 3.69E-14