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Author(s):   Jeong, K.-M.; Hsu, K.-J.; Jeffries, J.B.; Kaufman, F.
Title:   Kinetics of the reactions of OH with C2H6, CH3CCl3, CH2ClCHCl2, CH2ClCClF2, and CH2FCF3
Journal:   J. Phys. Chem.
Volume:   88
Year:   1984
Reference type:   Journal article
Squib:   1984JEO/HSU1222

Reaction:   CH3CCl3 + ·OHH2O + CCl3CH2
Reaction order:   2
Temperature:   278 - 457 K
Rate expression:   5.03x10-12 [±1.21x10-12 cm3/molecule s] e-14966 [±598 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
278 7.76E-15
300 1.25E-14
325 1.98E-14
350 2.94E-14
375 4.14E-14
400 5.59E-14
425 7.28E-14
450 9.22E-14
457 9.80E-14