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Author(s):   Finlayson-Pitts, B.J.; Ezell, M.J.; Jayaweera, T.M.; Berko, H.N.; Lai, C.C.
Title:   Kinetics of the reactions of OH with methyl chloroform and methane: implications for global tropospheric OH and the methane budget
Journal:   Geophys. Res. Lett.
Volume:   19
Page(s):   1371 - 1374
Year:   1992
Reference type:   Journal article
Squib:   1992FIN/EZE1371-1374

Reaction:   CH3CCl3 + ·OHH2O + CCl3CH2
Reaction order:   2
Temperature:   278 - 378 K
Pressure:  1.40E-3 bar
Rate expression:   9.1x10-13 [±4.65x10-13 cm3/molecule s] e-11141 [±1222 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
278 7.34E-15
300 1.05E-14
325 1.47E-14
350 1.98E-14
375 2.55E-14
378 2.63E-14