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Accessibility information
Author(s):   Jiang, Z.; Taylor, P.H.; Dellinger, B.
Title:   Laser photolysis/laser-induced fluorescence studies of the reaction of OH with 1,1,1-trichloroethane over an extended temperature range
Journal:   J. Phys. Chem.
Volume:   96
Page(s):   8961 - 8964
Year:   1992
Reference type:   Journal article
Squib:   1992JIA/TAY8961-8964

Reaction:   CH3CCl3 + ·OHH2O + CCl3CH2
Reaction order:   2
Temperature:   298 - 761 K
Pressure:  0.99 bar
Rate expression:   3.95x10-13 [±7.97x10-14 cm3/molecule s] (T/298 K)2.08 e-8896 [±890 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 1.09E-14
300 1.13E-14
325 1.76E-14
350 2.60E-14
375 3.67E-14
400 5.02E-14
425 6.67E-14
450 8.64E-14
475 1.10E-13
500 1.36E-13
525 1.67E-13
550 2.02E-13
575 2.41E-13
600 2.85E-13
625 3.33E-13
650 3.86E-13
675 4.44E-13
700 5.06E-13
725 5.74E-13
750 6.47E-13
761 6.81E-13