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Author(s):   Talukdar, r.K.; Mellouki, A.; Schmoltner, A-M.; Watson, T.; Montzka, S.; Ravishankara, A.R.
Title:   Kinetics of the OH reaciton with methyl chloroform and its atmospheric implications
Journal:   Science
Volume:   257
Page(s):   227 - 230
Year:   1992
Reference type:   Journal article
Squib:   1992TAL/MEL227-230

Reaction:   CH3CCl3 + ·OHH2O + CCl3CH2
Reaction order:   2
Temperature:   243 - 379 K
Pressure:  3.33E-2 - 1.00E-1 bar
Rate expression:   1.74x10-12 [±3.32x10-13 cm3/molecule s] e-12887 [±515 J/mole]/RT
Uncertainty:   1.08000004
Bath gas:   CH3CCl3
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
243 2.96E-15
250 3.54E-15
275 6.22E-15
300 9.94E-15
325 1.48E-14
350 2.08E-14
375 2.79E-14
379 2.92E-14