Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Atkinson, R.; Baulch, D.L.; Cox, R.A.; Hampson, R.F., Jr.; Kerr, J.A.; Rossi, M.J.; Troe, J.
Title:   Evaluated kinetic, photochemical and heterogeneous data for atmospheric chemistry: supplement V, IUPAC subcommittee on gas kinetic data evaluation for atmospheric chemistry
Journal:   J. Phys. Chem. Ref. Data
Volume:   26
Page(s):   521 - 1011
Year:   1997
Reference type:   Journal article
Squib:   1997ATK/BAU521-1011

Reaction:   CH3CCl3 + ·OHH2O + CCl3CH2
Reaction order:   2
Temperature:   240 - 300 K
Rate expression:   1.2x10-12 [cm3/molecule s] e-11973 [±1680 J/mole]/RT
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
240 2.98E-15
250 3.78E-15
275 6.39E-15
300 9.88E-15