Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Stutz, J.; Ezell, M.J.; Finlayson-Pitts, B.J.
Title:   Inverse kinetic isotope effect in the reaction of atomic chlorine with C2H4 and C2D4
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   9187 - 9190
Year:   1997
Reference type:   Journal article
Squib:   1997STU/EZE9187-9190

Reaction:   C2H4 + ·Cl → Products
Reaction order:   2
Reference reaction:   CH4 + ·Cl·CH3 + HCl
Temperature:   295 K
Pressure:  1.33E-3 bar
Rate expression:   2.91x10-13 [±1.99x10-13 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.