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Author(s):   Stutz, J.; Ezell, M.J.; Ezell, A.A.; Filayson-Pitts, B.J.
Title:   Rate constants and kinetic isotope effects in the reactions of atomic chlorine with n-butane and simple alkenes at room temperature
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   8510 - 8519
Year:   1998
Reference type:   Journal article
Squib:   1998STU/EZE8510-8519

Reaction:   C2H4 + ·Cl → Products
Reaction order:   2
Reference reaction:   1-C4H10 + ·Cl → Other Products + HCl
Temperature:   293 K
Pressure:  1.33E-3 bar
Rate expression:   9.9x10-11 [±1.1x10-11 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Gas chromatography

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