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Author(s):   Iwasaki, E.; Chiba, H.; Nakayama, T.; Matsumi, Y.; Wallington, T.J.
Title:   PLP-LIF study of the reactions of chlorine atoms with C2H2, C2H4, and C3H6 in 2-100 Torr of N2 diluent at 295 K
Journal:   Chem. Phys. Lett.
Volume:   494
Page(s):   174 - 178
Year:   2010
Reference type:   Journal article
Squib:   2010IWA/CHI174-178

Reaction:   C2H4 + ·Cl → Products
Reaction order:   2
Temperature:   298 K
Pressure:  6.67E-3 - 2.67E-2 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure dependent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Rate constant increases with pressure from 2.5×10-12 to 7.6×10-12 cm3 molecule-1 s-1.

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