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 Author(s):   Tsang, W.
Title:   Chemical kinetic data base for combustion chemistry. Part 3. Propane
Journal:   J. Phys. Chem. Ref. Data
Volume:   17
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988TSA887

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1988TSA887   CH2O + 2-C3H7 → C3H8 + HCO  300 - 2500   1.79E-13       2.91E04      2
  1988TSA887   CH2O + 1-C3H7 → C3H8 + HCO  300 - 2500   7.49E-14   2.90   2.45E04      2
  1988TSA887   CH3OH + 2-C3H7 → C3H8 + CH3O·  300 - 2500   1.12E-15   3.10   4.32E04      2
  1988TSA887   CH3OH + 2-C3H7 → C3H8 + (·)CH2OH  300 - 2500   7.57E-14   3.70   4.41E04      2
  1988TSA887   CH3OH + 1-C3H7 → C3H8 + CH3O·  300 - 2500   1.12E-15   3.10   3.74E04      2
  1988TSA887   CH3OH + 1-C3H7 → C3H8 + (·)CH2OH  300 - 2500   3.90E-15   3.17   3.83E04      2
  1988TSA887   CH4 + 2-C3H7 → C3H8 + ·CH3  300 - 2500   9.25E-17   4.40   4.51E04      2
  1988TSA887   CH4 + 1-C3H7 → C3H8 + ·CH3  300 - 2500   3.54E-16   4.02   4.55E04      2
  1988TSA887   C2H6 + 2-C3H7 → C3H8 + ·C2H5  300 - 2500   3.45E-14   4.20   3.65E04      2
  1988TSA887   C2H6 + 1-C3H7 → C3H8 + ·C2H5  300 - 2500   1.19E-15   3.82   3.78E04      2
  1988TSA887   C2H4 + 2-C3H7 → CH3CH=CH2 + ·C2H5  300 - 2500   4.40E-14       2.76E04      2
    1988TSA887   C2H4 + 1-C3H7 → C2H4 + 2-C3H7                      
  1988TSA887   C2H2 + 2-C3H7 → 1,3-Butadiene + ·CH3  300 - 2500   4.60E-14       2.72E04      2
  1988TSA887   C2H2 + 1-C3H7 → Other Products + C2H4  300 - 2500   1.20E-12       3.77E04      2
  1988TSA887   C3H8 → ·C2H5 + ·CH3  300 - 2500   2.78E18   -1.80   3.71E05      1
  1988TSA887   C3H8 + 2-C3H7 → C3H8 + 1-C3H7  300 - 2500   3.45E-16   4.20   3.65E04      2
  1988TSA887   C3H8 + ·C2H → C2H2 + 2-C3H7  300 - 2500   2.01E-12              2
  1988TSA887   C3H8 + ·C2H → C2H2 + 1-C3H7  300 - 2500   5.99E-12              2
  1988TSA887   C3H8 + CH3O2· → 2-C3H7 + CH3OOH  300 - 2500   3.30E-12       7.13E04      2
  1988TSA887   C3H8 + CH3O2· → 1-C3H7 + CH3OOH  300 - 2500   1.00E-11       8.11E04      2
  1988TSA887   C3H8 + 1-C3H7 → C3H8 + 2-C3H7  300 - 2500   1.10E-17   4.00   1.98E04      2
  1988TSA887   C3H8 + CH3O· → CH3OH + 2-C3H7  300 - 2500   2.41E-13       1.91E04      2
  1988TSA887   C3H8 + CH3O· → CH3OH + 1-C3H7  300 - 2500   7.21E-13       2.70E04      2
  1988TSA887   C3H8 + ·CH3 → CH4 + 2-C3H7  300 - 2500   9.10E-16   3.46   2.29E04      2
  1988TSA887   C3H8 + ·CH3 → CH4 + 1-C3H7  300 - 2500   1.61E-15   3.65   2.99E04      2
  1988TSA887   C3H8 + (·)CH2OH → CH3OH + 2-C3H7  300 - 2500   1.99E-15   2.95   5.01E04      2
  1988TSA887   C3H8 + (·)CH2OH → CH3OH + 1-C3H7  300 - 2500   6.56E-15   2.95   5.85E04      2
  1988TSA887   C3H8 + HCO → CH2O + 2-C3H7  300 - 2500   9.05E-13   1.90   7.12E04      2
  1988TSA887   C3H8 + HCO → CH2O + 1-C3H7  300 - 2500   5.21E-13   2.50   7.72E04      2
  1988TSA887   C3H8 + C2H3 → C2H4 + 2-C3H7  300 - 2500   7.95E-14   3.10   3.69E04      2
  1988TSA887   C3H8 + C2H3 → C2H4 + 1-C3H7  300 - 2500   1.46E-13   3.30   4.39E04      2
  1988TSA887   C3H8 + CH3CO → CH3CHO + 2-C3H7  300 - 2500   7.82E-13   2.00   6.79E04      2
  1988TSA887   C3H8 + CH3CO → CH3CHO + 1-C3H7  300 - 2500   1.89E-13   2.60   7.39E04      2
  1988TSA887   C3H8 + HO2 → 2-C3H7 + H2O2  300 - 2500   4.33E-14   2.60   5.82E04      2
  1988TSA887   C3H8 + HO2 → 1-C3H7 + H2O2  300 - 2500   1.61E-13   2.55   6.90E04      2
  1988TSA887   C3H8 + ·OH → 1-C3H7 + H2O  300 - 2500   0.56   -0.10   3725      2
  Reference reaction:  C3H8 + ·OH → 2-C3H7 + H2O 2
  1988TSA887   C3H8 + O2 → 2-C3H7 + HO2  300 - 2500   6.59E-11       2.00E05      2
  1988TSA887   C3H8 + O2 → 1-C3H7 + HO2  300 - 2500   6.59E-11       2.13E05      2
  1988TSA887   C3H8 + H· → H2 + 2-C3H7  298 - 2500   1.88E-12   2.40   1.87E04   9.87E-16  2
  1988TSA887   C3H8 + H· → H2 + 1-C3H7  298 - 2500   4.23E-12   2.54   2.83E04   4.70E-17  2
  1988TSA887   C3H8 + ·C2H5 → C2H6 + 2-C3H7  300 - 2500   7.29E-16   3.46   3.13E04      2
  1988TSA887   C3H8 + ·C2H5 → C2H6 + 1-C3H7  300 - 2500   1.61E-15   3.65   3.82E04      2
  1988TSA887   C3H8 + O· → 2-C3H7 + ·OH  300 - 2500   4.02E-13   2.71   8813      2
  1988TSA887   C3H8 + O· → 1-C3H7 + ·OH  300 - 2500   1.37E-12   2.68   1.55E04      2
  1988TSA887   C3H8 + ·CH2 → 2-C3H7 + ·CH3  300 - 2500   9.10E-16   3.46   3.13E04      2
  1988TSA887   C3H8 + ·CH2 → 1-C3H7 + ·CH3  300 - 2500   1.61E-15   3.65   2.99E04      2
  1988TSA887   H2 + 2-C3H7 → C3H8 + H·  300 - 2500   7.57E-15   3.28   3.63E04      2
  1988TSA887   H2 + 1-C3H7 → C3H8 + H·  300 - 2500   3.19E-14   2.84   3.82E04      2
  1988TSA887   2-C3H7 → CH3CH=CH2 + H·  300 - 2500   1.60E13       1.50E05      1
  1988TSA887   2-C3H7 → CH3CH=CH2 + H·  300 - 2500   1.10       -2.08E04      1
  Reference reaction:  2-C3H7 → C2H4 + ·CH3 1
  1988TSA887   2-C3H7 + 2-C3H7 → C3H8 + CH3CH=CH2  300 - 2500   6.51E-12   -0.70          2
  1988TSA887   2-C3H7 + 2-C3H7 → C3H8 + CH3CH=CH2  300 - 2500   0.65              2
  Reference reaction:  2-C3H7 + 2-C3H7 → 2,3-Dimethylbutane 2
  1988TSA887   2-C3H7 + 2-C3H7 → 2,3-Dimethylbutane  300 - 2500   1.00E-11   -0.70          2
  1988TSA887   2-C3H7 + ·C2H → C2H2 + CH3CH=CH2  300 - 2500   5.99E-12              2
  1988TSA887   2-C3H7 + CH3O2· → CH3CHO + CH3O· + ·CH3  300 - 2500   4.00E-11              2
  1988TSA887   2-C3H7 + 1-C3H7 → C3H8 + CH3CH=CH2  300 - 2500   1.16E-11   -0.35          2
  1988TSA887   2-C3H7 + 1-C3H7 → C3H8 + CH3CH=CH2  300 - 2500   0.40              2
  Reference reaction:  2-C3H7 + 1-C3H7 → (CH3)2CH(CH2)2CH3 2
  1988TSA887   2-C3H7 + 1-C3H7 → (CH3)2CH(CH2)2CH3  300 - 2500   2.91E-11   -0.35          2
  1988TSA887   2-C3H7 + CH3O· → CH2O + C3H8  300 - 2500   2.01E-11              2
  1988TSA887   2-C3H7 + CH3O· → iso-C3H7OCH3  300 - 2500   1.00E-11              2
  1988TSA887   2-C3H7 + ·CH3 → CH4 + CH3CH=CH2  300 - 2500   7.52E-12   0.68          2
  1988TSA887   2-C3H7 + ·CH3 → CH4 + CH3CH=CH2  300 - 2500   0.16              2
  Reference reaction:  2-C3H7 + ·CH3 → iso-C4H10 2
  1988TSA887   2-C3H7 + ·CH3 → iso-C4H10  300 - 2500   4.70E-11   -0.68          2
  1988TSA887   2-C3H7 + (·)CH2OH → CH2O + C3H8  300 - 2500   3.90E-12              2
  1988TSA887   2-C3H7 + (·)CH2OH → CH3OH + CH3CH=CH2  300 - 2500   4.80E-12              2
  1988TSA887   2-C3H7 + (·)CH2OH → iso-C4H9OH  300 - 2500   2.41E-11              2
  1988TSA887   2-C3H7 + HCO → C3H8 + CO  300 - 2500   2.01E-10              2
  1988TSA887   2-C3H7 + HCO → CH3CH2CH2CHO  300 - 2500   3.01E-11              2
  1988TSA887   2-C3H7 + C2H3 → Products  300 - 2500   2.61E-11   -0.70          2
  1988TSA887   2-C3H7 + C2H3 → C2H4 + CH3CH=CH2  300 - 2500   4.68E-12   -0.70          2
  1988TSA887   2-C3H7 + C2H3 → C2H4 + CH3CH=CH2  300 - 2500   0.18              2
  Reference reaction:  2-C3H7 + C2H3 → Products 2
  1988TSA887   2-C3H7 + C2H3 → C2H2 + C3H8  300 - 2500   4.68E-12   -0.70          2
  1988TSA887   2-C3H7 + C2H3 → C2H2 + C3H8  300 - 2500   0.18              2
  Reference reaction:  2-C3H7 + C2H3 → Products 2
  1988TSA887   2-C3H7 + CH3CO → 3-methyl-2-butanone  300 - 2500   1.50E-11   -0.35          2
  1988TSA887   2-C3H7 + HO2 → CH3CHO + ·CH3 + ·OH  300 - 2500   4.00E-11              2
  1988TSA887   2-C3H7 + ·OH → CH3CH=CH2 + H2O  300 - 2500   4.00E-11              2
  1988TSA887   2-C3H7 + H2O2 → C3H8 + HO2  300 - 2500   4.82E-15   2.83   1.70E04      2
  1988TSA887   2-C3H7 + O2 → CH3CH=CH2 + HO2  700 - 2500   2.09E-13              2
  1988TSA887   2-C3H7 + H· → CH3CH=CH2 + H2  300 - 2500   5.99E-12              2
  1988TSA887   2-C3H7 + ·C2H5 → C2H6 + CH3CH=CH2  300 - 2500   5.20E-12   -0.35          2
  1988TSA887   2-C3H7 + ·C2H5 → C2H6 + CH3CH=CH2  300 - 2500   0.20              2
  Reference reaction:  2-C3H7 + ·C2H5 → iso-C5H12 2
  1988TSA887   2-C3H7 + ·C2H5 → C2H4 + C3H8  300 - 2500   4.17E-12   -0.35          2
  1988TSA887   2-C3H7 + ·C2H5 → C2H4 + C3H8  300 - 2500   0.16              2
  Reference reaction:  2-C3H7 + ·C2H5 → iso-C5H12 2
  1988TSA887   2-C3H7 + ·C2H5 → iso-C5H12  300 - 2500   2.61E-11   -0.35          2
  1988TSA887   2-C3H7 + O· → Products  300 - 2500   1.60E-10              2
  1988TSA887   2-C3H7 + O· → Acetone + H·  300 - 2500   8.00E-11              2
  1988TSA887   2-C3H7 + O· → Acetone + H·  300 - 2500   1.00              2
  Reference reaction:  2-C3H7 + O· → CH3CHO + ·CH3 2
  1988TSA887   2-C3H7 + O· → CH3CHO + ·CH3  300 - 1500   8.00E-11              2
  1988TSA887   2-C3H7 + ·CH2 → CH3CH=CH2 + ·CH3  300 - 2500   5.00E-11              2
  1988TSA887   ·C2H + 1-C3H7 → C2H2 + CH3CH=CH2  300 - 2500   1.00E-11              2
  1988TSA887   ·C2H + 1-C3H7 → ·C2H5 + ·CH2C≡CH  300 - 2500   2.01E-11              2
  1988TSA887   CH3O2· + 1-C3H7 → CH2O + ·C2H5 + CH3O·  300 - 2500   5.99E-11              2
  1988TSA887   1-C3H7 → C2H4 + ·CH3  300 - 2500   1.20E13       1.26E05      1
  1988TSA887   1-C3H7 → C2H4 + ·CH3  300 - 2500   1.10       -2.08E04      1
  Reference reaction:  1-C3H7 → CH3CH=CH2 + H· 1
  1988TSA887   1-C3H7 + 1-C3H7 → C3H8 + CH3CH=CH2  300 - 2500   2.81E-12              2
  1988TSA887   1-C3H7 + 1-C3H7 → 1-C6H14  300 - 2500   1.69E-11              2
  1988TSA887   1-C3H7 + CH3O· → CH2O + C3H8  300 - 2500   4.00E-11              2
  1988TSA887   1-C3H7 + CH3O· → CH3CH2CH2OCH3  300 - 2500   1.60E-11              2
  1988TSA887   1-C3H7 + ·CH3 → CH4 + CH3CH=CH2  300 - 2500   3.07E-12   -0.32          2
  1988TSA887   1-C3H7 + ·CH3 → 1-C4H10  300 - 2500   5.16E-11   -0.32          2
  1988TSA887   1-C3H7 + (·)CH2OH → CH2O + C3H8  300 - 2500   1.60E-12              2
  1988TSA887   1-C3H7 + (·)CH2OH → CH3OH + CH3CH=CH2  300 - 2500   8.00E-13              2
  1988TSA887   1-C3H7 + (·)CH2OH → CH3CH2CH2CH2OH  300 - 2500   1.60E-11              2
  1988TSA887   1-C3H7 + HCO → C3H8 + CO  300 - 2500   1.00E-10              2
  1988TSA887   1-C3H7 + HCO → CH3CH2CH2CHO  300 - 2500   2.01E-11              2
  1988TSA887   1-C3H7 + C2H3 → C2H4 + CH3CH=CH2  300 - 2500   2.01E-12              2
  1988TSA887   1-C3H7 + C2H3 → C2H2 + C3H8  300 - 2500   2.01E-12              2
  1988TSA887   1-C3H7 + C2H3 → 1-C5H10  300 - 2500   1.60E-11              2
  1988TSA887   1-C3H7 + CH3CO → 2-pentanone  300 - 2500   3.60E-11              2
  1988TSA887   1-C3H7 + HO2 → ·OH + n-C3H7O  300 - 2500   4.00E-11              2
  1988TSA887   1-C3H7 + ·OH → CH3CH2CH2OH  300 - 2500   4.00E-11              2
  1988TSA887   1-C3H7 + ·OH → CH3CH=CH2 + H2O  300 - 2500   4.00E-11              2
  1988TSA887   1-C3H7 + H2O2 → C3H8 + HO2  300 - 2500   5.15E-15   2.11   1.07E04      2
  1988TSA887   1-C3H7 + O2 → CH3CH=CH2 + HO2  500 - 900   1.50E-13              2
  1988TSA887   1-C3H7 + O2 → n-C3H7O2  300 - 550   5.65E-12   -2.70          2
  1988TSA887   1-C3H7 + H· → CH3CH=CH2 + H2  300 - 2500   3.01E-12              2
  1988TSA887   ·C2H5 + 1-C3H7 → C2H6 + CH3CH=CH2  300 - 2500   2.41E-12              2
  1988TSA887   ·C2H5 + 1-C3H7 → C2H4 + C3H8  303 - 2500   1.91E-12              2
  1988TSA887   ·C2H5 + 1-C3H7 → n-C5H12  300 - 2500   3.30E-11              2
  1988TSA887   1-C3H7 + O· → Products  300 - 2500   1.60E-10              2
  1988TSA887   1-C3H7 + O· → C2H5CHO + H·  300 - 2500   6.00              2
  Reference reaction:  1-C3H7 + O· → CH2O + ·C2H5 2
  1988TSA887   1-C3H7 + ·CH2 → C2H4 + ·C2H5  300 - 2500   3.01E-11              2
  1988TSA887   1-C3H7 + ·CH2 → CH3CH=CH2 + ·CH3  300 - 2500   3.01E-12              2
Search returned 123 records.