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Author(s):   Wilson, E.W.; Hamilton, W.A.; Kennington, H.R.; Evans, B.; Scott, N.W.; DeMore, W.B.
Title:   Measurement and estimation of rate constants for the reactions of hydroxyl radical with several alkanes and cycloalkanes
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   3593 - 3604
Year:   2006
Reference type:   Journal article
Squib:   2006WIL/HAM3593-3604

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2006WIL/HAM3593-3604   iso-C4H10 + ·OH → Products  229 - 403   3.18E-12   1.12   1013   2.12E-12  2
  2006WIL/HAM3593-3604   iso-C5H12 + ·OH → Products  213 - 407   3.46E-12   1.27   -131   3.65E-12  2
  2006WIL/HAM3593-3604   (CH3)2CH(CH2)2CH3 + ·OH → Products  283 - 398   1.96E-11       3184   5.42E-12  2
  2006WIL/HAM3593-3604   (C2H5)2CHCH3 + ·OH → Products  283 - 398   1.77E-11       2744   5.85E-12  2
  2006WIL/HAM3593-3604   2,3-Dimethylbutane + ·OH → Products  220 - 407   8.16E-12   0.42   748   6.03E-12  2
  2006WIL/HAM3593-3604   2,3-Dimethylpentane + ·OH → Products  287 - 403   1.95E-11       2735   6.46E-12  2
  2006WIL/HAM3593-3604   Pentane, 2,4-dimethyl- + ·OH → Products  272 - 410   2.49E-11       3683   5.63E-12  2
  2006WIL/HAM3593-3604   2,3,4-Trimethylpentane + ·OH → Products  244 - 373   9.85E-12       1031   6.50E-12  2
  2006WIL/HAM3593-3604   1-C7H16 + ·OH → Products  241 - 406   3.38E-11       4132   6.38E-12  2
  2006WIL/HAM3593-3604   n-C8H18 + ·OH → Products  284 - 393   4.52E-11       4473   7.43E-12  2
  2006WIL/HAM3593-3604   Cyclopentane + ·OH → Products  209 - 407   2.67E-11       4232   4.84E-12  2
  2006WIL/HAM3593-3604   Cyclohexane + ·OH → Products  225 - 408   3.10E-11       3916   6.38E-12  2
  2006WIL/HAM3593-3604   Cycloheptane + ·OH → Products  274 - 408   4.81E-11       3800   1.04E-11  2

Search returned 13 records.