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Author(s):   Yano, T.; Tschuikow-Roux, E.
Title:   Competitive photochlorination of the fluoroethanes CH3CHF2, CH2FCH2F and CHF2CHF2
Journal:   J. Photochem.
Volume:   32
Year:   1986
Reference type:   Journal article
Squib:   1986YAN/TSC25

Reaction:   CH2FCH2F + ·ClHCl + CH2FCHF
Reaction order:   2
Reference reaction:   C2H6 + ·Cl → Products
Temperature:   280 - 360 K
Pressure:  1.07E-2 - 1.37E-2 bar
Rate expression:   2.99x10-11 [±2.99x10-12 cm3/molecule s] e-9146 [±274 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
280 5.88E-13
300 7.64E-13
325 1.01E-12
350 1.29E-12
360 1.41E-12