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 Author(s):   Goldfinger, P.; Martens, G.
Title:   Elementary Rate Constants in Atomic Chlorination Reactions Part 3.-Bond Dissociation Energies and Entropies of the Activated State
Journal:   Trans. Faraday Soc.
Page(s):   2220 - 2225
Year:   1961
Reference type:   Journal article
Squib:   1961GOL/MAR2220-2225

Reaction:   C2C4H2 → C2HCl3 + HCl
Reaction order:   1
Temperature:   536 - 635 K
Rate expression:   4.0x1012 [s-1] e-202087 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Comments:   consistent with other data.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
536 8.10E-8
550 2.57E-7
575 1.75E-6
600 1.02E-5
625 5.16E-5
635 9.52E-5