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Author(s):   Chuchani, G.; Rotinov, A.; Martin, I.; Avila, I.; Dominquez, R.M.
Title:   Influence of polar α substituents in the gas-phase pyrolysis kinetics of tertiary chlorides. Correlation of alkyl and polar groups
Journal:   J. Phys. Chem.
Volume:   89
Page(s):   4134 - 4137
Year:   1985
Reference type:   Journal article
Squib:   1985CHU/ROT4134-4137

Reaction:   (CH3)2CClCH2ClCH2=C(CH3)CH2Cl + HCl
Reaction order:   1
Temperature:   613 - 693 K
Pressure:  6.13E-2 - 0.29 bar
Rate expression:   1.94x1014 [s-1] e-207862 [±6228 J/mole]/RT
Uncertainty:   3.3900001
Category:  Uncategorized

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
613 3.77E-4
625 8.24E-4
650 3.84E-3
675 1.60E-2
693 4.17E-2