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Author(s):   Kraus, J.W.; Calvert, J.G.
Title:   The disproportionation and combination reactions of butyl free radicals
Journal:   J. Am. Chem. Soc.
Volume:   79
Page(s):   5921 - 5926
Year:   1957
Reference type:   Journal article
Squib:   1957KRA/CAL5921-5926

Reaction:   tert-C4H9 + tert-C4H9iso-C4H10 + Isobutene
Reaction order:   2
Reference reaction:   tert-C4H9 + tert-C4H92,2,3,3-Tetramethylbutane
Reference reaction order:   2
Temperature:   375 - 595 K
Pressure:  1.33E-2 - 5.47E-2 bar
Rate expression:   4.59
Bath gas:   (t-C4H9)2CO
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

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