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Author(s):   James, D.G.L.; Suart, R.D.
Title:   Comparative study of the photolysis of 2,2'-azoisobutar and azomethane
Journal:   Trans. Faraday Soc.
Volume:   65
Year:   1969
Reference type:   Journal article
Squib:   1969JAM/SUA175

Reaction:   tert-C4H9 + tert-C4H9iso-C4H10 + Isobutene
Reaction order:   2
Reference reaction:   tert-C4H9 + tert-C4H92,2,3,3-Tetramethylbutane
Reference reaction order:   2
Temperature:   297 - 400 K
Rate expression:   1.58 e1039 [±8314472 J/mole]/RT
Uncertainty:   1.01999998
Bath gas:   (tert-C4H9N)2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
297 2.41E0
300 2.40E0
325 2.32E0
350 2.26E0
375 2.21E0
400 2.16E0