Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article

Citation

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   James, D.G.L.; Suart, R.D.
Title:   Comparative study of the photolysis of 2,2'-azoisobutar and azomethane
Journal:   Trans. Faraday Soc.
Volume:   65
Page(s):  
Year:   1969
Reference type:   Journal article
Squib:   1969JAM/SUA175

Reaction:   tert-C4H9 + tert-C4H9iso-C4H10 + Isobutene
Reaction order:   2
Reference reaction:   tert-C4H9 + tert-C4H92,2,3,3-Tetramethylbutane
Reference reaction order:   2
Temperature:   297 - 400 K
Rate expression:   1.58 e1039 [±8314472 J/mole]/RT
Uncertainty:   1.01999998
Bath gas:   (tert-C4H9N)2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
297 2.41E0
300 2.40E0
325 2.32E0
350 2.26E0
375 2.21E0
400 2.16E0