Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Enami, S.; Hashimoto, S.; Kawasaki, M.; Nakano, Y.; Ishiwata, T.; Tonokura, K.; Wallington, T.J.
Title:   Observation of adducts in the reaction of Cl atoms with XCH2I (X = H, CH3, Cl, Br, I) using cavity ring-down spectroscopy
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   1587 - 1593
Year:   2005
Reference type:   Journal article
Squib:   2005ENA/HAS1587-1593

Reaction:   CH3I + ·Cl → Adduct
Reaction order:   2
Temperature:   250 K
Pressure:  3.33E-2 bar
Rate expression:   4.0x10-12 [±1.0x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure dependent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Other (Vis-UV)
Comments:   Cavity ring-down measurement of reaction. Cl atoms generated by laser photolysis of Cl2 and adduct formation monitored at 435 nm.

View full bibliographic record.