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Accessibility information
Author(s):   Lim, K.P.; Michael, J.V.
Title:   Thermal decomposition of COCl2
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   211 - 215
Year:   1994
Reference type:   Journal article
Squib:   1994LIM/MIC211-215

Reaction:   COCl2ClCO + ·Cl
Reaction order:   1
Temperature:   1400 - 2000 K
Pressure:  8.00E-3 - 2.13E-2 bar
Rate expression:   5.71x1015 [s-1] e-302647 [J/mole]/RT
Bath gas:   He
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1400 2.92E4
1450 7.15E4
1500 1.65E5
1550 3.61E5
1600 7.52E5
1650 1.50E6
1700 2.87E6
1750 5.29E6
1800 9.42E6
1850 1.63E7
1900 2.73E7
1950 4.46E7
2000 7.12E7