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Author(s):   Lizardo-Huerta, J.-C.; Sirjean, B.; Verdier, L.; Fournet, R.; Glaude, P.-A.
Title:   Thermal Decomposition of Phosgene and Diphosgene
Journal:   J. Phys. Chem. A
Volume:   122
Page(s):   249 - 257
Year:   2018
Reference type:   Journal article
Squib:   2018LIZ/SIR249-257

Reaction:   COCl2ClCO + ·Cl
Reaction order:   2
Temperature:   300 - 2000 K
Rate expression:   4.65x10-7 [cm3/molecule s] e-513502 [J/mole]/RT
Category:  Theory
Data type:   High or low pressure extrapolation
Pressure dependence:   Rate constant is low pressure limit
Comments:   Extrapolation of literature data.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 1.82E-96
400 4.10E-74
500 1.06E-60
600 9.21E-52
700 2.24E-45
800 1.38E-40
900 7.33E-37
1000 7.00E-34
1100 1.92E-31
1200 2.07E-29
1300 1.08E-27
1400 3.23E-26
1500 6.11E-25
1600 8.01E-24
1700 7.76E-23
1800 5.84E-22
1900 3.55E-21
2000 1.80E-20