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Accessibility information
Author(s):   Herron, J.T.
Title:   Evaluated chemical kinetic data for the reactions of atomic oxygen O(3P) with saturated organic compounds in the gas phase
Journal:   J. Phys. Chem. Ref. Data
Volume:   17
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988HER967

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1988HER967   CH2O + O· → HCO + ·OH  250 - 800   2.99E-11       1.28E04   1.70E-13  2
  1988HER967   CH2O + O· → HCO + ·OH  800 - 2000   3.45E-12   1.94   4340      2
  1988HER967   CCl4 + O· → ·CCl3 + ClO  300 - 1000   4.98E-13       1.83E04      2
  1988HER967   Diethyl ether + O· → Other Products + ·OH  300 - 500   9.96E-11       1.66E04      2
  1988HER967   C2H5OH + O· → Other Products + ·OH  300 - 1000   1.22E-12   2.46   7732      2
  1988HER967   CH3OH + O· → Other Products + ·OH  1000 - 2000   6.11E-13   2.50   1.29E04      2
  1988HER967   CH3OH + O· → Other Products + ·OH  300 - 1000   3.32E-11       2.10E04      2
  1988HER967   iso-C3H7OH + O· → Other Products + ·OH  298   6.64E-14           6.64E-14  2
  1988HER967   Acetone + O· → CH3C(O)CH2(·) + ·OH  300 - 700   1.66E-11       2.49E04      2
  1988HER967   CHCl3 + O· → ·CCl3 + ·OH  300 - 1000   4.98E-12       2.08E04      2
  1988HER967   CH3CH2CH2OH + O· → Other Products + ·OH  298   4.98E-14           4.98E-14  2
  1988HER967   CH3CH2CH2CH2OH + O· → Other Products + ·OH  300 - 600   4.98E-11       1.50E04      2
  1988HER967   CH4 + O· → ·CH3 + ·OH  400 - 2500   8.30E-12   1.56   3.55E04      2
  1988HER967   CH3Br + O· → ·OH + ·CH2Br  400 - 1500   3.32E-11       3.24E04      2
  1988HER967   C2H6 + O· → ·C2H5 + ·OH  1100 - 2000   3.89E-12   2.40   2.44E04      2
  1988HER967   C2H6 + O· → ·C2H5 + ·OH  400 - 1100   1.83E-10       3.28E04      2
  1988HER967   CH3Cl + O· → ·OH + ·CH2Cl  400 - 1500   3.32E-11       3.24E04      2
  1988HER967   CH3NH2 + O· → Products  300 - 600   8.97E-12       6901      2
  1988HER967   C2H5Br + O· → Other Products + ·OH  340 - 650   5.15E-11       2.71E04      2
  1988HER967   C3H8 + O· → Other Products + ·OH  1100 - 2000   3.64E-13   3.50   1.06E04      2
  1988HER967   C3H8 + O· → Other Products + ·OH  400 - 1100   1.66E-10       2.64E04      2
  1988HER967   C2H5Cl + O· → Other Products + ·OH  340 - 650   7.97E-11       2.77E04      2
  1988HER967   C2H5NH2 + O· → Products  300 - 600   1.13E-11       5321      2
  1988HER967   CH3CHO + O· → Other Products + ·OH  300 - 500   1.19E-11       8231      2
  1988HER967   CH2Cl2 + O· → ·OH + CHCl2  300 - 1000   9.96E-12       2.41E04      2
  1988HER967   Cyclopropane + O· → Cyclopropyl + ·OH  298   8.30E-16           8.30E-16  2
  1988HER967   Oxirane + O· → ·OH + Oxiranyl  298   6.64E-17           6.64E-17  2
  1988HER967   (CH3)3NBH3 + O· → Products  300 - 2000   4.98E-11              2
  1988HER967   iso-C3H7Br + O· → ·OH + (CH3)2CBr  340 - 650   3.82E-11       2.24E04      2
  1988HER967   iso-C4H10 + O· → Other Products + ·OH  1000 - 2000   6.44E-14   3.90   665      2
  1988HER967   iso-C4H10 + O· → Other Products + ·OH  400 - 1000   9.47E-11       2.20E04      2
  1988HER967   iso-C3H7Cl + O· → ·OH + (CH3)2CCl  300 - 700   3.99E-11       2.13E04      2
  1988HER967   CH3CHCl2 + O· → Other Products + ·OH  300 - 700   4.98E-12       2.03E04      2
  1988HER967   CHFCl2 + O· → ·CCl2F + ·OH  300 - 1000   1.66E-11       3.08E04      2
  1988HER967   COCl2 + O· → ClCO + ClO  292   9.96E-15              2
  1988HER967   CHF2Cl + O· → ·CClF2 + ·OH  300 - 1000   1.16E-11       3.49E04      2
  1988HER967   CHF3 + O· → ·CF3 + ·OH  300 - 1000   8.30E-12       4.49E04      2
  1988HER967   (CH3)3N + O· → Products  300 - 600   1.08E-11       -1746      2
  1988HER967   CF3Br + O· → ·CF3 + BrO  500 - 1500   1.49E-11       5.65E04      2
  1988HER967   tert-C4H9OH + O· → Other Products + ·OH  300 - 600   8.30E-12       1.83E04      2
  1988HER967   CH3CF2Cl + O· → Other Products + ·OH  298   6.64E-17           6.64E-17  2
  1988HER967   CF3CH2Cl + O· → ·OH + CF3CHCl  300 - 700   3.32E-12       2.16E04      2
  1988HER967   iso-C4H9Br + O· → Other Products + ·OH  340 - 600   5.65E-11       2.09E04      2
  1988HER967   iso-C5H12 + O· → Other Products + ·OH  307   1.33E-13              2
  1988HER967   iso-C4H9OH + O· → Other Products + ·OH  300 - 600   6.14E-12       9146      2
  1988HER967   (CH3)2CHCHO + O· → Other Products + ·OH  300 - 500   1.31E-11       6070      2
  1988HER967   sec-C4H9Cl + O· → Other Products + ·OH  340 - 650   5.98E-11       2.10E04      2
  1988HER967   sec-C4H9OH + O· → Other Products + ·OH  300 - 600   7.47E-12       9977      2
  1988HER967   C2H5COCH3 + O· → Other Products + ·OH  300 - 600   8.30E-13       1.08E04      2
  1988HER967   CH3C(O)OCH3 + O· → Other Products + ·OH  300 - 500   1.66E-11       2.41E04      2
  1988HER967   2,3-Dimethylbutane + O· → Other Products + ·OH  300 - 2000   3.09E-13   3.60   1164      2
  1988HER967   (C2H5)2CO + O· → Other Products + ·OH  300 - 600   4.98E-13       8314      2
  1988HER967   1-C4H10 + O· → Other Products + ·OH  300 - 2000   3.49E-13   3.90   6485      2
  1988HER967   CH2ClCH2Cl + O· → ·OH + CH2ClCHCl·  300 - 700   8.30E-12       2.08E04      2
  1988HER967   HC(O)OCH3 + O· → HC(O)OCH2(·) + ·OH  300 - 500   1.49E-11       2.24E04      2
  1988HER967   Pentane, 2,4-dimethyl- + O· → Other Products + ·OH  307   1.66E-13              2
  1988HER967   Cyclohexanone + O· → Other Products + ·OH  300 - 600   4.98E-11       1.91E04      2
  1988HER967   CH3COOCH2CH2CH3 + O· → Other Products + ·OH  300 - 500   2.66E-11       2.00E04      2
  1988HER967   n-C4H9Br + O· → Other Products + ·OH  340 - 650   7.31E-11       2.23E04      2
  1988HER967   n-C5H12 + O· → Other Products + ·OH  300 - 2000   1.68E-12   3.00   8398      2
  1988HER967   HC(O)OC2H5 + O· → Other Products + ·OH  300 - 500   1.66E-11       2.16E04      2
  1988HER967   Tetrahydrofuran + O· → Other Products + ·OH  300 - 600   1.33E-10       1.58E04      2
  1988HER967   1-C6H14 + O· → Other Products + ·OH  300 - 2000   2.49E-12   2.90   8314      2
  1988HER967   Cyclohexane + O· → Cyclohexyl + ·OH  300 - 2000   1.17E-11   2.60   1.07E04      2
  1988HER967   n-C8H18 + O· → Other Products + ·OH  300 - 2000   2.67E-12   2.80   6984      2
  1988HER967   Dimethyl ether + O· → ·OH + CH3OCH2·  300 - 500   8.30E-11       1.91E04      2
  1988HER967   Cyclopentanone + O· → Other Products + ·OH  300 - 600   3.99E-11       1.91E04      2
  1988HER967   C2H5CHO + O· → Other Products + ·OH  300 - 500   1.30E-11       7234      2
  1988HER967   CH3CH2CH2CHO + O· → Other Products + ·OH  300 - 500   1.66E-11       7150      2
  1988HER967   (CH3)2NH + O· → Products  300 - 600   1.51E-11       2328      2
  1988HER967   CH3C(O)OC2H5 + O· → Other Products + ·OH  300 - 500   2.32E-11       2.08E04      2
  1988HER967   Tetrahydro-2H-pyran + O· → Other Products + ·OH  300 - 600   9.96E-11       1.50E04      2
  1988HER967   1-C7H16 + O· → Other Products + ·OH  300 - 2000   2.31E-12   2.90   7317      2
  1988HER967   Spiropentane + O· → ·OH + Spiropentyl  298 - 650   6.64E-11       2.40E04   4.08E-15  2
  1988HER967   Cyclobutane + O· → ·OH + Cyclobutyl  298   1.16E-14           1.16E-14  2
  1988HER967   Cyclopentane + O· → ·OH + Cyclopentyl  300 - 2000   1.30E-11   2.60   1.16E04      2
  1988HER967   Cycloheptane + O· → ·OH + Cycloheptyl  300 - 2000   9.45E-12   2.60   9063      2
  1988HER967   neo-C5H12 + O· → ·OH + Neopentyl  1000 - 2000   3.57E-12   2.50   2.26E04      2
  1988HER967   neo-C5H12 + O· → ·OH + Neopentyl  400 - 1000   1.53E-10       2.99E04      2
  1988HER967   tert-C4H9Cl + O· → ·OH + (CH3)2CClCH2  340 - 650   4.32E-11       2.50E04      2
  1988HER967   iso-C4H9Cl + O· → Other Products + ·OH  340 - 650   5.98E-11       2.10E04      2
  1988HER967   2,2,4-Trimethylpentane + O· → Other Products + ·OH  307   9.13E-14              2
  1988HER967   2,3,4-Trimethylpentane + O· → Other Products + ·OH  307   4.98E-14              2
  1988HER967   2,2-Dimethylpentane + O· → Other Products + ·OH  307   1.08E-13              2
  1988HER967   CH2FCl + O· → ·OH + ·CClFH  300 - 1000   8.30E-12       2.58E04      2
  1988HER967   (CH3)2Hg + O· → Products  298   2.49E-11           2.49E-11  2
  1988HER967   2,2,3,3-Tetramethylbutane + O· → ·OH + (CH3)3CC(CH3)2CH2  300 - 2000   8.15E-12   2.50   2.14E04      2
  1988HER967   t-C4H9CH2Cl + O· → Other Products + ·OH  340 - 650   5.31E-11       2.22E04      2
  1988HER967   (CH3)3SiH + O· → ·OH + (CH3)3Si·  298   2.66E-12           2.66E-12  2
  1988HER967   (CH3)6Si2 + O· → Products  298   1.30E-13           1.30E-13  2
  1988HER967   tert-C4H9 + O· → Products  300 - 2000   8.30E-10              2
  1988HER967   ·CClF + O· → Products  298   1.66E-11           1.66E-11  2
  1988HER967   (C2H5)3NBH3 + O· → Products  300 - 2000   4.98E-11              2
  1988HER967   FCO + O· → Products  300 - 2000   9.96E-11              2
  1988HER967   2-C3H7 + O· → Products  300 - 2000   4.98E-10              2
  1988HER967   CH3O2· + O· → CH3O· + O2  300 - 2000   8.30E-11              2
  1988HER967   1-C3H7 + O· → Products  300 - 2000   3.32E-10              2
  1988HER967   CH3O· + O· → Products  300 - 2000   3.32E-11              2
  1988HER967   ·CF2 + O· → Products  298   1.66E-11           1.66E-11  2
  1988HER967   ·CH3 + O· → CH2O + H·  300 - 2000   1.39E-10              2
  1988HER967   ·CF3 + O· → COF2 + ·F  298   3.32E-11           3.32E-11  2
  1988HER967   CF3I + O· → ·CF3 + IO  300 - 1500   1.16E-11              2
  1988HER967   CH3CH(·)OH + O· → Products  300 - 2000   1.66E-10              2
  1988HER967   (·)CH2OH + O· → Products  300 - 2000   8.30E-11              2
  1988HER967   HCO + O· → Products  300 - 2000   9.96E-11              2
  1988HER967   Cyclohexyl + O· → Products  300 - 2000   3.32E-10              2
  1988HER967   CH3CO + O· → Products  300 - 2000   9.96E-11              2
  1988HER967   ·CCl3 + O· → COCl2 + ·Cl  298   4.15E-11           4.15E-11  2
  1988HER967   ·CH + O· → Products  300 - 2000   9.96E-11              2
  1988HER967   Neopentyl + O· → Products  300 - 2000   3.32E-10              2
  1988HER967   ·CCl + O· → CO + ·Cl  300 - 2000   9.96E-11              2
  1988HER967   iso-C4H9 + O· → Products  300 - 2000   3.32E-10              2
  1988HER967   (CH3)2C(·)OH + O· → Products  300 - 2000   8.30E-11              2
  1988HER967   GeH4 + O· → ·OH + GeH3  298   3.32E-12           3.32E-12  2
  1988HER967   SiH4 + O· → ·OH + SiH3  300 - 1000   6.64E-12       6652      2
  1988HER967   BH3CO + O· → Products  298   6.64E-13           6.64E-13  2
  1988HER967   ·CHF + O· → Products  300 - 2000   1.49E-10              2
  1988HER967   ·C2H5 + O· → Products  300 - 2000   2.16E-10              2
  1988HER967   O· + Diborane(6) → Products  300 - 1000   1.66E-11       2.08E04      2
  1988HER967   O· + (CH3)2CCl → Products  300 - 2000   1.66E-10              2
  1988HER967   O· + n-C7H15Cl → Other Products + ·OH  298   1.33E-13           1.33E-13  2
  1988HER967   O· + ·CH2 → Products  300 - 2000   1.33E-10              2
Search returned 122 records.