NIST Chemical Kinetics Database

Author(s):   Baulch, D.L.; Cobos, C.J.; Cox, R.A.; Frank, P.; Hayman, G.; Just, Th.; Kerr, J.A.; Murrells, T.; Pilling, M.J.; Troe, J.; Walker, R.W.; Warnatz, J.
Title:   Evaluated kinetic data for combusion modelling. Supplement I
Journal:   J. Phys. Chem. Ref. Data
Volume:   23
Page(s):   847 - 1033
Year:   1994
Reference type:   Journal article
Squib:   1994BAU/COB847-1033

Reaction:   CH₃O₂· + CH₃O₂· → CH₃O· + CH₃O· + O₂
Reaction order:   2
Reference reaction:   CH₃O₂· + CH₃O₂· → CH₂O + CH₃OH + O₂
Reference reaction order:   2
Temperature:   298 - 700 K
Rate expression:   2.5x10¹ e^{-9728 [J/mole]/RT}
Category: Theory
Data type:   Estimated: thermochemical, kinetic, or other

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) []
298	4.93E-1
300	5.06E-1
325	6.83E-1
350	8.83E-1
375	1.10E0
400	1.34E0
425	1.59E0
450	1.86E0
475	2.13E0
500	2.41E0
525	2.69E0
550	2.98E0
575	3.27E0
600	3.56E0
625	3.85E0
650	4.13E0
675	4.42E0
700	4.70E0