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Author(s):   Good, D.A.; Hansen, J.; Kamoboures, M.; Santiono, R.; Francisco, J.S.
Title:   An Experimental and Computational Study of the Kinetics and Mechanism of the Reaction of Methyl Formate with Cl Atoms
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   1505 - 1511
Year:   2000
Reference type:   Journal article
Squib:   2000GOO/HAN1505-1511

Reaction:   HC(O)OCH3 + ·Cl → Products
Reaction order:   2
Reference reaction:   CH2Cl2 + ·Cl → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  2.80E-2 bar
Rate expression:   1.43x10-12±6.7x10-13
Bath gas:   O2
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)

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