Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Wallington, T.J.; Hurley, M.D.; Ball, J.C.; Straccia, A.M.; Platz, J.; Christensen, L.K.; Sehested, J.; Nielsen, O.J.
Title:   Atmospheric chemistry of dimethoxymethane (CH3OCH2OCH3): kinetics and mechanism of its reaction with OH radicals and fate of the alkoxy radicals CH3OCHO(.)OCH3 and CH3OCH2OCH2O(.)
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   5302 - 5308
Year:   1997
Reference type:   Journal article
Squib:   1997WAL/HUR5302-5308

Reaction:   CH3OCH2OCH3 + ·Cl → Other Products + HCl
Reaction order:   2
Reference reaction:   1-C4H10 + ·Cl → Other Products + HCl
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   1.35x10-10 [±1.48x10-11 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.