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Author(s):   Brokenshire, J.L.; Nechvatal, A.; Tedder, J.M.
Title:   Free-radical substitution in aliphatic compounds. Part 20.-Gas-phase photolytic chlorination of butane and 2-methylpropane by t-butyl hypochlorite
Journal:   Trans. Faraday Soc.
Volume:   66
Year:   1970
Reference type:   Journal article
Squib:   1970BRO/NEC2029

Reaction:   iso-C4H10 + (CH3)3CO· → tert-C4H9OH + iso-C4H9
Reaction order:   2
Temperature:   283 - 343 K
Pressure:  0.27 bar
Rate expression:   1.73x10-13 [cm3/molecule s] e-26024 [J/mole]/RT
Bath gas:   tert-C4H9OCl
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
283 2.72E-18
300 5.08E-18
325 1.13E-17
343 1.88E-17