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Author(s):   Chuchani, G.; Martin, I.; Rotinov, A.; Dominguez, R.M.
Title:   Elimination kinetics and mechanism of primary, secondary and tertiary α-hydroxycarboxylic acids in the gas phase
Journal:   J. Phys. Org. Chem.
Volume:   6
Page(s):   54 - 58
Year:   1993
Reference type:   Journal article
Squib:   1993CHU/MAR54-58

Reaction:   (CH3)2COHCOOHAcetone + CO + H2O
Reaction order:   1
Temperature:   553 - 603 K
Pressure:  4.07E-2 - 0.27 bar
Rate expression:   8.13x1012 [s-1] e-174604 [±1746 J/mole]/RT
Uncertainty:   1.350000023841858
Bath gas:   Cyclohexene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
553 2.62E-4
575 1.12E-3
600 5.13E-3
603 6.10E-3