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Title: Elimination kinetics and mechanism of primary, secondary and tertiary α-hydroxycarboxylic acids in the gas phase
Journal: J. Phys. Org. Chem.
Volume: 6
Page(s): 54 - 58
Year: 1993
Reference type: Journal article
Squib: 1993CHU/MAR54-58
Reaction:
(CH3)2COHCOOH → Acetone + CO + H2O
Reaction order:
1
Temperature:
553 - 603
K
Pressure: 4.07E-2 - 0.27 bar
Rate expression:
8.13x1012 [s-1] e-174604 [±1746 J/mole]/RT
Uncertainty:
1.350000023841858
Bath gas:
Cyclohexene
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 553 | 2.62E-4 |
| 575 | 1.12E-3 |
| 600 | 5.13E-3 |
| 603 | 6.10E-3 |