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Accessibility information
Author(s):   Brown, T.C.; King, K.D.
Title:   Very low-pressure pyrolysis (VLPP) of methyl- and ethynyl- cyclopentanes and cyclohexanes
Journal:   Int. J. Chem. Kinet.
Volume:   21
Page(s):   251 - 266
Year:   1989
Reference type:   Journal article
Squib:   1989BRO/KIN251-266

Reaction:   Methylcyclopentane·CH3 + Cyclopentyl
Reaction order:   1
Temperature:   1020 - 1220 K
Rate expression:   1.26x1012 [s-1] e-368331 [±11058 J/mole]/RT
Uncertainty:   2.0
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1020 1.73E-7
1025 2.14E-7
1050 5.99E-7
1075 1.60E-6
1100 4.08E-6
1125 9.97E-6
1150 2.35E-5
1175 5.33E-5
1200 1.17E-4
1220 2.14E-4