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Accessibility information
Author(s):   Brown, T.C.; King, K.D.
Title:   Very low-pressure pyrolysis (VLPP) of methyl- and ethynyl- cyclopentanes and cyclohexanes
Journal:   Int. J. Chem. Kinet.
Volume:   21
Page(s):   251 - 266
Year:   1989
Reference type:   Journal article
Squib:   1989BRO/KIN251-266

Reaction:   Cyclopentane, ethynyl- → Isomers + CH2=CH(CH2)3C≡CH
Reaction order:   1
Temperature:   925 - 1210 K
Rate expression:   1.0x1016 [s-1] e-304310 [±9146 J/mole]/RT
Uncertainty:   2.0
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
925 6.55E-2
950 1.85E-1
975 4.98E-1
1000 1.27E0
1025 3.11E0
1050 7.27E0
1075 1.64E1
1100 3.55E1
1125 7.43E1
1150 1.51E2
1175 2.97E2
1200 5.68E2
1210 7.30E2