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Author(s):   Vedeneev, V.I.; Teitel'boim, M.A.; Shoikhet, A.A.
Title:   Competition in reactions of the CF3 radical with oxygen and fluorine
Journal:   Bull. Acad. Sci. USSR Div. Chem. Sci. (Engl. Transl.)
Page(s):   480 - 482
Year:   1977
Reference type:   Journal article
Squib:   1977VED/TEI480-482

Reaction:   ·CF3 + O2CF3O2
Reaction order:   2
Reference reaction:   ·CF3 + F2CF4 + ·F
Reference reaction order:   2
Temperature:   256 - 345 K
Pressure:  6.67E-2 - 0.71 bar
Rate expression:   8.2x10-1±7.4x10-2 e10559 [±209525 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Pressure measurement

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
256 1.17E2
275 8.31E1
300 5.65E1
325 4.08E1
345 3.25E1