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Title: Competition in reactions of the CF3 radical with oxygen and fluorine
Journal: Bull. Acad. Sci. USSR Div. Chem. Sci. (Engl. Transl.)
Page(s): 480 - 482
Year: 1977
Reference type: Journal article
Squib: 1977VED/TEI480-482
Reaction:
·CF3 + O2 → CF3O2
Reaction order:
2
Reference reaction:
·CF3 + F2 → CF4 + ·F
Reference reaction order:
2
Temperature:
256 - 345
K
Pressure: 6.67E-2 - 0.71 bar
Rate expression:
8.2x10-1±7.4x10-2 e10559 [±209525 J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 256 | 1.17E2 |
| 275 | 8.31E1 |
| 300 | 5.65E1 |
| 325 | 4.08E1 |
| 345 | 3.25E1 |