Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article

Citation

Help

Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...

Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

 Author(s):   Kaiser, E.W.;Donahue, C.J.;Pala, I.R.;Wallington, T.J.;Hurley, M.D.
Title:   Kinetics, products, and stereochemistry of the reaction of chlorine atoms with cis- and trans-2-butene in 10-700 torr of N2 or N2/O2 diluent at 297 k
Journal:   J. Phys. Chem. A
Volume:   111
Page(s):   1286 - 1299
Year:   2007
Reference type:   Journal article
Squib:   2007KAI/DON1286-1299

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2007KAI/DON1286-1299   CH3CH=CHCH3 + ·Cl → Products  297   1.36              2
  Reference reaction:  CH3CH=CH2 + ·Cl → Products 2
  2007KAI/DON1286-1299   CH3CH=CHCH3 + ·Cl → Products  297   3.58E-10              2
  2007KAI/DON1286-1299   (E)-2-C4H8 + ·Cl → Products  297   3.27E-10              2
  2007KAI/DON1286-1299   (Z)-2-C4H8 + ·Cl → Products  297   3.13E-10              2
  2007KAI/DON1286-1299   (E)-2-C4H8 + ·Cl → Products  297   2.27              2
  Reference reaction:  C3H8 + ·Cl → Products 2
  2007KAI/DON1286-1299   (Z)-2-C4H8 + ·Cl → Products  297   2.20              2
  Reference reaction:  C3H8 + ·Cl → Products 2
  2007KAI/DON1286-1299   (E)-2-C4H8 + ·Cl → Products  297   2.03              2
  Reference reaction:  C3H8 + ·Cl → Products 2
  2007KAI/DON1286-1299   (Z)-2-C4H8 + ·Cl → Products  297   1.87              2
  Reference reaction:  C3H8 + ·Cl → Products 2
  2007KAI/DON1286-1299   (E)-2-C4H8 + ·Cl → Products  297   2.90E-10              2
  2007KAI/DON1286-1299   (Z)-2-C4H8 + ·Cl → Products  297   2.70E-10              2
  2007KAI/DON1286-1299   (E)-2-C4H8 + ·Cl → Products  297   3.10E-10              2
  2007KAI/DON1286-1299   (Z)-2-C4H8 + ·Cl → Products  297   3.50E-10              2
  2007KAI/DON1286-1299   (E)-2-C4H8 + ·Cl → Products  297   3.60              2
  Reference reaction:  CH3CH=CH2 + ·Cl → Products 2
  2007KAI/DON1286-1299   (Z)-2-C4H8 + ·Cl → Products  297   4.00              2
  Reference reaction:  CH3CH=CH2 + ·Cl → Products 2
  2007KAI/DON1286-1299   CH3CHClCH=CH2 + ·Cl → Products  297   2.10E-10              2
  2007KAI/DON1286-1299   1-chloro-2-butene + ·Cl → Products  297   2.20E-10              2
  2007KAI/DON1286-1299   CH3CHClCHClCH3 + ·Cl → Products  297   1.10E-11              2
Search returned 17 records.