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Accessibility information
Author(s):   Frank-Kamenetskii, D.A.
Title:   Thermal reactions of C2H2. I. Kinetics and the mechanism of the thermal polymerization of C2H2 and of its reaction with NO
Journal:   Zh. Fiz. Khim.
Volume:   18
Year:   1944
Reference type:   Journal article
Squib:   1944FRA329

Reaction:   C2H2 + NO → Products
Reaction order:   2
Temperature:   673 - 973 K
Pressure:  6.67E-2 - 0.13 bar
Rate expression:   9.27x10-4 [cm3/molecule s] e-266063 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
673 2.07E-24
675 2.39E-24
700 1.30E-23
725 6.28E-23
750 2.74E-22
775 1.08E-21
800 3.94E-21
825 1.32E-20
850 4.14E-20
875 1.21E-19
900 3.35E-19
925 8.76E-19
950 2.18E-18
973 4.83E-18