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Title: Kinetics of the hydrogen abstraction from propane, n-butane, isobutane, and cyclopentane by difluoroamino-radicals
Journal: J. Chem. Soc. A
Page(s):
Year: 1971
Reference type: Journal article
Squib: 1971CAD/DOD2967
Reaction:
Cyclopentyl + HNF2 → Cyclopentane + NF2
Reaction order:
2
Temperature:
374 - 446
K
Pressure: 1.33E-2 - 7.20E-2 bar
Rate expression:
9.33x10-14 [cm3/molecule s] e-13719 [±8730 J/mole]/RT
Uncertainty:
2.28999996
Bath gas:
Cyclopentane
Category: Experiment
Data type:
Derived from detailed balance/reverse rate
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 374 | 1.13E-15 |
| 375 | 1.15E-15 |
| 400 | 1.51E-15 |
| 425 | 1.92E-15 |
| 446 | 2.31E-15 |