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Author(s):   Dijkstra, A.J.; Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   Reactions of difluoroamino-radicals. Part III. Addition to olefins
Journal:   J. Chem. Soc. A
Year:   1967
Reference type:   Journal article
Squib:   1967DIJ/KER105

Reaction:   C2H5CHCH2NF21-C4H8 + NF2
Reaction order:   1
Reference reaction:   NF2 + C2H5CHCH2NF2CH3CH2CH(NF2)CH2NF2
Reference reaction order:   2
Temperature:   334 - 428 K
Rate expression:   7.59x1022 [molecule/cm3] e-43069 [J/mole]/RT
Bath gas:   N2F4
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [molecule/cm3]
334 1.40E16
350 2.84E16
375 7.60E16
400 1.80E17
425 3.86E17
428 4.21E17