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Title: Kinetics of the combination reactions of chlorofluoromethylperoxy radicals with NO2 in the temperature range 233-373 K
Journal: J. Chem. Soc. Faraday Trans. 2
Volume: 84
Page(s):
Year: 1988
Reference type: Journal article
Squib: 1988CAR/LES569
Reaction:
NO2 + CClF2OO → CClF2OONO2
Reaction order:
3
Temperature:
233 - 373
K
Pressure: 1.33E-3 - 1.33E-2 bar
Rate expression:
4.0x10-29 [±1.99x10-29 cm6/molecule2 s] (T/298 K)(-5.10±1.00)
Bath gas:
O2
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm6/molecule2 s] |
|---|---|
| 233 | 1.40E-28 |
| 250 | 9.79E-29 |
| 275 | 6.02E-29 |
| 300 | 3.86E-29 |
| 325 | 2.57E-29 |
| 350 | 1.76E-29 |
| 373 | 1.27E-29 |