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Title: Recombination of CF3, C2F5 and C3F7 in helium and argon
Journal: Vestn. Leningr. Univ. Ser. 4: Fiz. Khim.
Volume: 1
Page(s): 30 - 37
Year: 1988
Reference type: Journal article
Squib: 1988SKO/SLE30-37
Reaction:
CF3CF2CF2· + I → CF3CF2CF2I
Reaction order:
2
Temperature:
296 - 456
K
Pressure: 5.33E-2 - 0.68 bar
Rate expression:
1.4x10-11 [±5.98x10-12 cm3/molecule s] (T/298 K)-0.50 e-831 [±831 J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Thermal
Analytical technique:
Other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 296 | 1.00E-11 |
| 300 | 1.00E-11 |
| 325 | 9.85E-12 |
| 350 | 9.71E-12 |
| 375 | 9.56E-12 |
| 400 | 9.41E-12 |
| 425 | 9.26E-12 |
| 450 | 9.12E-12 |
| 456 | 9.09E-12 |