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Title: Homogeneous decomposition of dialkylperoxides in oxygen
Journal: J. Chem. Soc. Faraday Trans. 2
Volume: 83
Page(s):
Year: 1987
Reference type: Journal article
Squib: 1987SAH/RIG2035
Reaction:
(n-C4H9)-OO-(n-C4H9) → CH3CH2CH2CH2O· + CH3CH2CH2CH2O·
Reaction order:
1
Temperature:
473 - 513
K
Pressure: 0.40 bar
Rate expression:
1.05x1016 [s-1] e-160469 [±11225 J/mole]/RT
Uncertainty:
3.0999999046325684
Bath gas:
O2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Electron spin resonance (ESR or EPR)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 473 | 2.00E-2 |
| 475 | 2.37E-2 |
| 500 | 1.81E-1 |
| 513 | 4.81E-1 |