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Title: The kinetics of the dehydrochlorination of substituted hydrocarbons. Part VII. The mechanism of the thermal decompositions of 1: 1: 2: 2- and 1: 1: 1: 2-tetrachloroethane
Journal: J. Chem. Soc.
Page(s): 2033 - 2038
Year: 1951
Reference type: Journal article
Squib: 1951BAR/HOW2033-2038
Reaction:
(CHCl2)2 → C2HCl3 + HCl
Reaction order:
1
Temperature:
536 - 655
K
Pressure: 2.53E-2 - 0.11 bar
Rate expression:
4.17x109 [s-1] e-152986 [J/mole]/RT
Bath gas:
(CHCl2)2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 536 | 5.15E-6 |
| 550 | 1.23E-5 |
| 575 | 5.28E-5 |
| 600 | 2.00E-4 |
| 625 | 6.83E-4 |
| 650 | 2.12E-3 |
| 655 | 2.63E-3 |