NIST Chemical Kinetics Database

Author(s):   Shvets, V.F.; Lebedev, N.N.; Aver'yanov, V.A.
Title:   Kinetics and mechanism of thermal decomposition of 1,1,2,2-tetrachlorethane and pentachlorethane in the gas phase
Journal:   Kinet. Catal.
Volume:   10
Page(s):   28 - 35
Year:   1969
Reference type:   Journal article
Squib:   1969SHV/LEB28-35

Reaction:   (CHCl₂)2 → C₂HCl₃ + HCl
Reaction order:   1
Temperature:   697 - 721 K
Rate expression:   1.0x10¹² [s^-1] e^{-182087 [J/mole]/RT}
Bath gas:   (CHCl2)2
Category: Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [s^-1]
697	2.26E-2
700	2.59E-2
721	6.43E-2