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Title: Reactions of Oxygenated Radicals in the Gas Phase. Part 1. Reaction of Peracetyl Radicals and But-2-ene
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s):
Year: 1975
Reference type: Journal article
Squib: 1975DIA/SEL758
Reaction:
(E)-2-C4H8 + CH3C(O)OO(·) → CH3C(O)O· + trans-2,3-Dimethyloxirane
Reaction order:
2
Temperature:
393
K
Pressure: 0.28 bar
Rate expression:
1.99x10-16 [±1.59x10-17 cm3/molecule s]
Bath gas:
O2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
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