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 Author(s):   Atkinson, R.
Title:   Kinetics and mechanisms of the gas-phase reactions of the hydroxyl radical with organic compounds under atmospheric conditions
Journal:   Chem. Rev.
Volume:   86
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986ATK69

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1986ATK69   CH2O + ·OH → HCO + H2O  228 - 426   9.00E-12           9.00E-12  2
  1986ATK69   C2H5OH + ·OH → Other Products + H2O  298 - 625   5.28E-12       1463   2.93E-12  2
  1986ATK69   CH3OH + ·OH → Other Products + H2O  298 - 420   1.34E-11       6693   8.99E-13  2
  1986ATK69   Acetone + ·OH → Products  300   2.31E-13              2
  1986ATK69   CHCl3 + ·OH → ·CCl3 + H2O  240 - 500   5.60E-13   2.00   4190   1.03E-13  2
  1986ATK69   Benzene + ·OH → Products  250 - 325   7.57E-12       4398   1.28E-12  2
  1986ATK69   Benzene + ·OH → Products  450 - 1000   2.89E-13   2.00   2860      2
  1986ATK69   CH3CCl3 + ·OH → H2O + CCl3CH2  250 - 420   5.26E-13   2.00   9395   1.19E-14  2
  1986ATK69   CH4 + ·OH → ·CH3 + H2O  238 - 1250   6.18E-13   2.00   1.06E04   8.42E-15  2
  1986ATK69   CH3Br + ·OH → H2O + ·CH2Br  240 - 350   7.41E-13       7275   3.93E-14  2
  1986ATK69   CH3Br + ·OH → H2O + ·CH2Br  240 - 350   1.04E-13   2.00   2461   3.86E-14  2
  1986ATK69   C2H6 + ·OH → ·C2H5 + H2O  238 - 850   1.22E-12   2.00   3692   2.75E-13  2
  1986ATK69   C2H4 + ·OH → Products  290 - 500   2.14E-12       -3417   8.51E-12  2
  1986ATK69   C2H2 + ·OH → Products  270 - 420   1.69E-12       1937   7.75E-13  2
  1986ATK69   C2H2 + ·OH → Products  270 - 420   1.91E-12       1937   8.74E-13  2
  1986ATK69   C2H2 + ·OH → Products  298   4.00E-30           4.00E-30  3
  1986ATK69   CH3Cl + ·OH → ·CH2Cl + H2O  250 - 500   3.11E-13   2.00   4864   4.36E-14  2
  1986ATK69   CH3SH + ·OH → Products  240 - 420   9.71E-12       -3043   3.32E-11  2
  1986ATK69   C3H8 + ·OH → Other Products + H2O  250 - 850   1.13E-12   2.00   -116   1.19E-12  2
  1986ATK69   C2H5Cl + ·OH → Other Products + H2O  298   4.00E-13           4.00E-13  2
  1986ATK69   CH3CN + ·OH → Products  250 - 433   6.77E-13       8647   2.07E-14  2
  1986ATK69   CH3CHO + ·OH → Products  298 - 426   6.87E-12       -2129   1.62E-11  2
  1986ATK69   C2H5SH + ·OH → Products  250 - 420   1.23E-11       -3293   4.65E-11  2
  1986ATK69   CH2Cl2 + ·OH → CHCl2 + H2O  250 - 500   7.54E-13   2.00   4157   1.41E-13  2
  1986ATK69   CH2F2 + ·OH → ·CHF2 + H2O  250 - 500   4.48E-13   2.00   9229   1.08E-14  2
  1986ATK69   (CH3)2S + ·OH → H2O + CH3SCH2  250 - 420   6.77E-12       1139   4.28E-12  2
  1986ATK69   iso-C4H10 + ·OH → Other Products + H2O  250 - 900   8.52E-13   2.00   -2536   2.37E-12  2
  1986ATK69   CH3CHF2 + ·OH → Other Products + H2O  295   3.40E-14              2
  1986ATK69   CHFCl2 + ·OH → ·CCl2F + H2O  240 - 500   1.51E-13   2.00   3983   3.03E-14  2
  1986ATK69   CHF2Cl + ·OH → ·CClF2 + H2O  250 - 500   1.34E-13   2.00   8314   4.67E-15  2
  1986ATK69   CHF3 + ·OH → ·CF3 + H2O  290 - 500   1.86E-13   2.00   1.70E04   1.91E-16  2
  1986ATK69   CH3CF2Cl + ·OH → CF2ClCH2· + H2O  270 - 420   1.83E-13   2.00   9728   3.60E-15  2
  1986ATK69   CF3CH2Cl + ·OH → H2O + CF3CHCl  280 - 420   7.56E-14   2.00   3808   1.62E-14  2
  1986ATK69   iso-C5H12 + ·OH → Other Products + H2O  298   3.90E-12           3.90E-12  2
  1986ATK69   CH2=C(CH3)CH=CH2 + ·OH → Products  290 - 422   2.54E-11       -3401   1.00E-10  2
  1986ATK69   Methacrolein + ·OH → Products  298 - 424   1.96E-11       -1114   3.07E-11  2
  1986ATK69   C2H5COCH3 + ·OH → Products  300   1.00E-12              2
  1986ATK69   CH2=CHCOCH3 + ·OH → Products  290 - 420   3.29E-12       -4274   1.85E-11  2
  1986ATK69   CHCl2CH2Cl + ·OH → Other Products + H2O  280 - 420   1.66E-12       4016   3.28E-13  2
  1986ATK69   CHCl2CH2Cl + ·OH → Other Products + H2O  280 - 420   1.57E-13   2.00   -1821   3.28E-13  2
  1986ATK69   C2HCl3 + ·OH → Products  234 - 420   5.63E-13       -3550   2.36E-12  2
  1986ATK69   2,3-Dimethylbutane + ·OH → Other Products + H2O  298 - 500   6.19E-12           6.19E-12  2
  1986ATK69   alpha-pinene + ·OH → Products  298 - 422   1.20E-11       -3692   5.33E-11  2
  1986ATK69   Naphthalene + ·OH → Products  298 - 410   1.05E-12       -7500   2.17E-11  2
  1986ATK69   Naphthalene + ·OH → Products  600 - 1000   9.96E-13   2.00   8057      2
  1986ATK69   Biphenyl + ·OH → Products  298   7.01E-12           7.01E-12  2
  1986ATK69   1,2-Dimethylbenzene + ·OH → Products  298 - 320   1.47E-11           1.47E-11  2
  1986ATK69   1,2-Dimethylbenzene + ·OH → Products  450 - 1000   1.55E-12   2.00   291      2
  1986ATK69   2-Methylphenol + ·OH → Products  300   4.00E-11              2
  1986ATK69   (C2H5)2CHCH3 + ·OH → Other Products + H2O  298   5.60E-12           5.60E-12  2
  1986ATK69   Ethylbenzene + ·OH → Products  298   7.51E-12           7.51E-12  2
  1986ATK69   Benzaldehyde + ·OH → Products  298   1.30E-11           1.30E-11  2
  1986ATK69   1-Phenylpropane + ·OH → Products  298   5.71E-12           5.71E-12  2
  1986ATK69   1,4-Dimethylbenzene + ·OH → Products  297 - 320   1.52E-11           1.52E-11  2
  1986ATK69   1,4-Dimethylbenzene + ·OH → Products  450 - 1000   1.55E-12   2.00   823      2
  1986ATK69   4-Methylphenol + ·OH → Products  300   4.40E-11              2
  1986ATK69   1-C4H10 + ·OH → Other Products + H2O  250 - 500   1.55E-11       4490   2.53E-12  2
  1986ATK69   1-C4H8 + ·OH → Products  280 - 420   6.54E-12       -3891   3.15E-11  2
  1986ATK69   1,3-Butadiene + ·OH → Products  299 - 424   1.39E-11       -3891      2
  1986ATK69   CH2=CHCHO + ·OH → Products  298   1.96E-11           1.96E-11  2
  1986ATK69   (CH3)2CH(CH2)2CH3 + ·OH → Other Products + H2O  298   5.50E-12           5.50E-12  2
  1986ATK69   Methyl Isobutyl Ketone + ·OH → Products  297   1.41E-11              2
  1986ATK69   1,3-Dimethylbenzene + ·OH → Products  250 - 325   1.66E-11       -964   2.45E-11  2
  1986ATK69   1,3-Dimethylbenzene + ·OH → Products  450 - 1000   1.52E-12   2.00   1056      2
  1986ATK69   3-Methylphenol + ·OH → Products  300   5.71E-11              2
  1986ATK69   (iso-C4H9)2CO + ·OH → Products  299   2.71E-11              2
  1986ATK69   Toluene + ·OH → Products  220 - 325   2.09E-12       -2677   6.16E-12  2
  1986ATK69   Toluene + ·OH → Products  450 - 1000   6.74E-13   2.00   -91.46      2
  1986ATK69   n-C5H12 + ·OH → Other Products + H2O  299   4.05E-12              2
  1986ATK69   Tetrahydrofuran + ·OH → Products  300   1.50E-11              2
  1986ATK69   Furan + ·OH → Products  250 - 420   1.32E-11       -2777   4.04E-11  2
  1986ATK69   Thiophene + ·OH → Products  250 - 420   3.20E-12       -2694   9.51E-12  2
  1986ATK69   1-C6H14 + ·OH → Other Products + H2O  298   5.58E-12           5.58E-12  2
  1986ATK69   Cyclohexane + ·OH → Cyclohexyl + H2O  290 - 500   2.71E-11       3243   7.31E-12  2
  1986ATK69   Cyclohexene + ·OH → Products  298   6.74E-11           6.74E-11  2
  1986ATK69   1-C8H18 + ·OH → Other Products + H2O  290 - 500   3.12E-11       3159   8.72E-12  2
  1986ATK69   1-C9H20 + ·OH → Other Products + H2O  298   1.00E-11           1.00E-11  2
  1986ATK69   CH3CH=CH2 + ·OH → Products  290 - 467   4.85E-12       -4190   2.63E-11  2
  1986ATK69   CH3CH=CH2 + ·OH → Products  701 - 896   3.30E-11       1.28E04      2
  1986ATK69   CH3CH=CH2 + ·OH → Products  960 - 1210   8.40E-11       2.39E04      2
  1986ATK69   Dimethyl ether + ·OH → H2O + CH3OCH2·  295 - 442   1.04E-11       3093   2.99E-12  2
  1986ATK69   Isobutene + ·OH → Products  297 - 424   9.51E-12       -4182   5.15E-11  2
  1986ATK69   C2H5CHO + ·OH → Products  298   1.96E-11           1.96E-11  2
  1986ATK69   1-C10H22 + ·OH → Other Products + H2O  298   1.12E-11           1.12E-11  2
  1986ATK69   C2Cl4 + ·OH → Products  250 - 420   9.65E-12       1.01E04   1.66E-13  2
  1986ATK69   beta-pinene + ·OH → Products  297 - 423   2.36E-11       -2968   7.81E-11  2
  1986ATK69   1-C7H16 + ·OH → Other Products + H2O  298   7.21E-12           7.21E-12  2
  1986ATK69   Cyclopentane + ·OH → Cyclopentyl + H2O  298   5.20E-12           5.20E-12  2
  1986ATK69   CF3CHCl2 + ·OH → H2O + CF3CCl2  280 - 420   1.16E-12       8813   3.31E-14  2
  1986ATK69   CH2=C=CH2 + ·OH → Products  299 - 421   5.86E-12       -1272      2
  1986ATK69   neo-C5H12 + ·OH → Neopentyl + H2O  250 - 900   1.55E-12   2.00   1488   8.50E-13  2
  1986ATK69   2,2,3-Trimethylbutane + ·OH → Other Products + H2O  290 - 500   1.12E-11       2494   4.10E-12  2
  1986ATK69   (CH3)2C=CHCH3 + ·OH → Products  298 - 425   1.93E-11       -3742   8.72E-11  2
  1986ATK69   2,2,4-Trimethylpentane + ·OH → Other Products + H2O  290 - 500   1.62E-11       3683   3.66E-12  2
  1986ATK69   (CH3)2CHCH=CH2 + ·OH → Products  299 - 423   5.33E-12       -4432      2
  1986ATK69   (CH3)2C=C(CH3)2 + ·OH → Products  298   1.10E-10           1.10E-10  2
  1986ATK69   (Z)-2-C4H8 + ·OH → Products  298 - 425   1.09E-11       -4057   5.60E-11  2
  1986ATK69   CH3F + ·OH → ·CH2F + H2O  290 - 480   4.88E-13   2.00   8314   1.70E-14  2
  1986ATK69   CH2FCl + ·OH → H2O + ·CClFH  250 - 500   3.35E-13   2.00   5022   4.42E-14  2
  1986ATK69   2,2,3,3-Tetramethylbutane + ·OH → H2O + (CH3)3CC(CH3)2CH2  290 - 750   1.66E-12   2.00   1106   1.06E-12  2
  1986ATK69   (E)-2-C4H8 + ·OH → Products  298 - 425   1.01E-11       -4565   6.37E-11  2
  1986ATK69   CF3CH2F + ·OH → H2O + CF3CHF  280 - 420   1.13E-13   2.00   6394   8.56E-15  2
  1986ATK69   Benzene-d6 + ·OH → Products  250 - 325   1.54E-12       748   1.14E-12  2
  1986ATK69   Benzene-d6 + ·OH → Products  450 - 1000   1.98E-13   2.00   4839      2
  1986ATK69   C6D5CD3 + ·OH → Products  250 - 325   7.32E-12       366   6.32E-12  2
  1986ATK69   C6D5CD3 + ·OH → Products  450 - 1000   6.08E-13   2.00   2295      2
  1986ATK69   S=C(CH3)SCH3 + ·OH → Products  249 - 367   5.11E-11       -3442   2.05E-10  2
  1986ATK69   CF3CHFCl + ·OH → CF3CFCl· + H2O  280 - 420   6.39E-13       1.02E04   1.03E-14  2
  1986ATK69   CF3CHFCl + ·OH → CF3CFCl· + H2O  280 - 420   8.10E-14   2.00   5188   9.98E-15  2
  1986ATK69   ·OH + (E)-CH3CH=CHCHO → Products  298   3.60E-11           3.60E-11  2
Search returned 110 records.