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Title: The reaction of OH radicals with 1,1-di-, tri- and tetrachloroethylene
Journal: Ber. Bunsenges. Phys. Chem.
Volume: 94
Page(s): 77 - 83
Year: 1990
Reference type: Journal article
Squib: 1990KIR/HEL77-83
Reaction:
C2HCl3 + ·OH → Products
Reaction order:
2
Temperature:
300 - 459
K
Pressure: 1.40E-3 - 8.20E-3 bar
Rate expression:
7.8x10-13 [±8.63x10-14 cm3/molecule s] e1995 [±499 J/mole]/RT
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 300 | 1.74E-12 |
| 325 | 1.63E-12 |
| 350 | 1.55E-12 |
| 375 | 1.48E-12 |
| 400 | 1.42E-12 |
| 425 | 1.37E-12 |
| 450 | 1.33E-12 |
| 459 | 1.32E-12 |