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Title: Laser photolysis/laser-induced fluorescence studies of the reaction of OH with 1,1,1,2- and 1,1,2,2-tetrachloroethane over an extended temperature range
Journal: J. Phys. Chem.
Volume: 97
Page(s): 5050 - 5053
Year: 1993
Reference type: Journal article
Squib: 1993JIA/TAY5050-5053
Reaction:
C2HCl3 + ·OH → Products
Reaction order:
2
Temperature:
293 - 403
K
Pressure: 0.99 bar
Rate expression:
1.26x10-13 [cm3/molecule s] e8564 [J/mole]/RT
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Laser induced fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 293 | 4.24E-12 |
| 300 | 3.90E-12 |
| 325 | 3.00E-12 |
| 350 | 2.39E-12 |
| 375 | 1.96E-12 |
| 400 | 1.66E-12 |
| 403 | 1.62E-12 |