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Author(s):   Jiang, Z.; Taylor, P.H.; Dellinger, B.
Title:   Laser photolysis/laser-induced fluorescence studies of the reaction of OH with 1,1,1,2- and 1,1,2,2-tetrachloroethane over an extended temperature range
Journal:   J. Phys. Chem.
Volume:   97
Page(s):   5050 - 5053
Year:   1993
Reference type:   Journal article
Squib:   1993JIA/TAY5050-5053

Reaction:   C2HCl3 + ·OH → Products
Reaction order:   2
Temperature:   293 - 403 K
Pressure:  0.99 bar
Rate expression:   1.26x10-13 [cm3/molecule s] e8564 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
293 4.24E-12
300 3.90E-12
325 3.00E-12
350 2.39E-12
375 1.96E-12
400 1.66E-12
403 1.62E-12