Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Teruel, M.A.; Achad, M.; Blanco, M.B.
Title:   Kinetic study of the reactions of Cl atoms with unsaturated carbonyl compounds at atmospheric pressure and structure activity relations (SARs)
Journal:   Chem. Phys. Lett.
Volume:   479
Page(s):   25 - 29
Year:   2009
Reference type:   Journal article
Squib:   2009TER/ACH25-29

Reaction:   CH2=CHC(O)OC2H5 + ·Cl → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   2.53x10-10 [±4.6x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   CH2CCl2 and CH2CHCN were used as reference compounds. Error limits are twice the standard deviations from least-squares fits with additional contribution from the uncertainties in the reference rate constants.

View full bibliographic record.