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Author(s):   Choi, Y.; Park, J.; Lin, M.C.
Title:   Kinetics and mechanism of the C6H5 + CH3CHO reaction: Experimental measurement and theoretical prediction of the reactivity towards four molecular sites
Journal:   ChemPhysChem
Volume:   5
Page(s):   661 - 668
Year:   2004
Reference type:   Journal article
Squib:   2004CHO/PAR661-668

Reaction:   CH3CHO + PhenylBenzene + CH2=CHO·
Reaction order:   2
Temperature:   298 - 2500 K
Rate expression:   1.46x10-14 [cm3/molecule s] (T/298 K)3.30 e-7899 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 6.01E-16
300 6.28E-16
400 3.58E-15
500 1.20E-14
600 3.01E-14
700 6.28E-14
800 1.16E-13
900 1.95E-13
1000 3.06E-13
1100 4.57E-13
1200 6.54E-13
1300 9.06E-13
1400 1.22E-12
1500 1.60E-12
1600 2.06E-12
1700 2.61E-12
1800 3.25E-12
1900 3.99E-12
2000 4.85E-12
2100 5.82E-12
2200 6.93E-12
2300 8.18E-12
2400 9.58E-12
2500 1.11E-11