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Title: The reaction of phenoxy radicals with mono-chlorobenzene and its meaning for gas-phase dioxin formation in incineration
Journal: Symp. Int. Combust. Proc.
Volume: 26
Page(s): 2405 - 2411
Year: 1996
Reference type: Journal article
Squib: 1996GRO/LOU2405-2411
Reaction:
C6H5O + C6H5O → Dibenzofuran + H2O
Reaction order:
2
Temperature:
728 - 984
K
Pressure: 1.01 bar
Rate expression:
2.66x10-10 [cm3/molecule s] e-46395 [J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Time resolution:
In both real time and by end product analysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 728 | 1.25E-13 |
| 750 | 1.56E-13 |
| 775 | 1.98E-13 |
| 800 | 2.48E-13 |
| 825 | 3.07E-13 |
| 850 | 3.74E-13 |
| 875 | 4.52E-13 |
| 900 | 5.39E-13 |
| 925 | 6.38E-13 |
| 950 | 7.47E-13 |
| 975 | 8.69E-13 |
| 984 | 9.15E-13 |