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Author(s):   Beach, S.D.; Hickson, K.M.; Smith, I.W.M.; Tuckett, R.P.
Title:   Rate Constants and Arrhenius Parameters for the Reactions of OH Radicals and Cl Atoms with CF3CH2OCHF2, CF3CHClOCHF2 and CF3CH2OCClF2, Using the Discharge-Flow/Resonance Fluorescence Method
Journal:   Phys. Chem. Chem. Phys.
Volume:   3
Page(s):   3064 - 3069
Year:   2001
Reference type:   Journal article
Squib:   2001BEA/HIC3064-3069

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2001BEA/HIC3064-3069   CF3CH2OCHF2 + ·OH → Products  292 - 402   2.00E-11       1.75E04   1.68E-14  2
  2001BEA/HIC3064-3069   ·OH + CHF2OCHClCF3 → Products  293 - 393   4.50E-13       7816   1.92E-14  2
  2001BEA/HIC3064-3069   CF3CH2OCClF2 + ·OH → Products  293 - 410   1.60E-12       9146   3.99E-14  2
  2001BEA/HIC3064-3069   1,2,2,2-tetrafluoroethyl trifluoromethyl ether + ·Cl → Products  294 - 398   6.10E-12       1.52E04   1.31E-14  2
  2001BEA/HIC3064-3069   ·Cl + CHF2OCHClCF3 → Products  318 - 399   7.80E-11       2.48E04      2
  2001BEA/HIC3064-3069   CF3CH2OCClF2 + ·Cl → Products  323 - 402   2.20E-11       2.24E04      2

Search returned 6 records.