Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Beach, S.D.; Hickson, K.M.; Smith, I.W.M.; Tuckett, R.P.
Title:   Rate Constants and Arrhenius Parameters for the Reactions of OH Radicals and Cl Atoms with CF3CH2OCHF2, CF3CHClOCHF2 and CF3CH2OCClF2, Using the Discharge-Flow/Resonance Fluorescence Method
Journal:   Phys. Chem. Chem. Phys.
Volume:   3
Page(s):   3064 - 3069
Year:   2001
Reference type:   Journal article
Squib:   2001BEA/HIC3064-3069

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2001BEA/HIC3064-3069   CF3CH2OCHF2 + ·OH → Products  292 - 402   2.00E-11       1.75E04   1.68E-14  2
  2001BEA/HIC3064-3069   ·OH + CHF2OCHClCF3 → Products  293 - 393   4.50E-13       7816   1.92E-14  2
  2001BEA/HIC3064-3069   CF3CH2OCClF2 + ·OH → Products  293 - 410   1.60E-12       9146   3.99E-14  2
  2001BEA/HIC3064-3069   1,2,2,2-tetrafluoroethyl trifluoromethyl ether + ·Cl → Products  294 - 398   6.10E-12       1.52E04   1.31E-14  2
  2001BEA/HIC3064-3069   ·Cl + CHF2OCHClCF3 → Products  318 - 399   7.80E-11       2.48E04      2
  2001BEA/HIC3064-3069   CF3CH2OCClF2 + ·Cl → Products  323 - 402   2.20E-11       2.24E04      2

Search returned 6 records.