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 Author(s):   Tsang, W.; Hampson, R.F.
Title:   Chemical kinetic data base for combustion chemistry. Part I. Methane and related compounds
Journal:   J. Phys. Chem. Ref. Data
Volume:   15
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986TSA/HAM1087

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1986TSA/HAM1087   CH2O → HCO + H·  1000 - 3000   1.69   -6.90   4.04E05      2
  1986TSA/HAM1087   CH2O + CH3O2· → HCO + CH3OOH  300 - 2500   3.30E-12       4.88E04      2
  1986TSA/HAM1087   CH2O + CH3O· → CH3OH + HCO  300 - 2500   1.69E-13       1.25E04      2
  1986TSA/HAM1087   CH2O + ·CH3 → CH4 + HCO  300 - 2500   8.25E-14   2.81   2.45E04      2
  1986TSA/HAM1087   CH2O + C2H3 → C2H4 + HCO  300 - 2500   8.07E-14   2.81   2.45E04      2
  1986TSA/HAM1087   CH2O + CH3CO → CH3CHO + HCO  300 - 2500   3.01E-13       5.40E04      2
  1986TSA/HAM1087   CH2O + HO2 → HCO + H2O2  300 - 2500   3.30E-12       4.88E04      2
  1986TSA/HAM1087   CH2O + ·OH → HCO + H2O  200 - 1600   4.75E-12   1.18   -1871   1.01E-11  2
  1986TSA/HAM1087   CH2O + O2 → HCO + HO2  300 - 2500   3.40E-11       1.63E05      2
  1986TSA/HAM1087   CH2O + H· → H2 + HCO  300 - 2500   8.72E-12   1.77   1.26E04      2
  1986TSA/HAM1087   CH2O + ·C2H5 → C2H6 + HCO  300 - 2500   8.19E-14   2.81   2.45E04      2
  1986TSA/HAM1087   CH2O + O· → HCO + ·OH  250 - 750   3.01E-11       1.29E04   1.66E-13  2
  1986TSA/HAM1087   CH2O + ·CH2 → ·CH3 + HCO  300 - 2500   <1.00E-14              2
  1986TSA/HAM1087   CH4 → ·CH3 + H·  300 - 2500   3.72E15       4.34E05      1
  1986TSA/HAM1087   CH4 + ·C2H → C2H2 + ·CH3  300 - 2500   3.01E-12       2079      2
  1986TSA/HAM1087   CH4 + CH3O2· → ·CH3 + CH3OOH  300 - 2500   3.01E-13       7.73E04      2
  1986TSA/HAM1087   CH4 + CH3O· → CH3OH + ·CH3  300 - 2500   2.61E-13       3.70E04      2
  1986TSA/HAM1087   CH4 + HCO → CH2O + ·CH3  300 - 2500   1.36E-13   2.85   9.40E04      2
  1986TSA/HAM1087   CH4 + C2H3 → C2H4 + ·CH3  300 - 2500   2.13E-14   4.02   2.29E04      2
  1986TSA/HAM1087   CH4 + CH3CO → CH3CHO + ·CH3  300 - 2500   4.82E-14   2.88   8.98E04      2
  1986TSA/HAM1087   CH4 + HO2 → ·CH3 + H2O2  300 - 2500   3.01E-13       7.77E04      2
  1986TSA/HAM1087   CH4 + ·OH → ·CH3 + H2O  300 - 2500   2.77E-13   2.40   8813      2
  1986TSA/HAM1087   CH4 + O2 → ·CH3 + HO2  300 - 2500   6.71E-11       2.38E05      2
  1986TSA/HAM1087   CH4 + H· → H2 + ·CH3  300 - 2500   9.86E-13   3.00   3.67E04      2
  1986TSA/HAM1087   CH4 + ·C2H5 → C2H6 + ·CH3  300 - 2500   2.51E-15   4.14   5.25E04      2
  1986TSA/HAM1087   CH4 + O· → ·CH3 + ·OH  300 - 2500   8.75E-12   1.50   3.60E04      2
  1986TSA/HAM1087   CH4 + ·CH2 → ·CH3 + ·CH3  300 - 2500   <3.01E-19              2
  1986TSA/HAM1087   C2H6 → ·CH3 + ·CH3  300 - 2500   1.18E18   -1.79   3.81E05      1
  1986TSA/HAM1087   C2H6 + ·C2H → C2H2 + ·C2H5  300 - 2500   5.99E-12              2
  1986TSA/HAM1087   C2H6 + CH3O2· → ·C2H5 + CH3OOH  300 - 2500   4.90E-13       6.25E04      2
  1986TSA/HAM1087   C2H6 + CH3O· → CH3OH + ·C2H5  300 - 2500   4.00E-13       2.97E04      2
  1986TSA/HAM1087   C2H6 + ·CH3 → CH4 + ·C2H5  300 - 2500   7.19E-15   4.00   3.47E04      2
  1986TSA/HAM1087   C2H6 + HCO → CH2O + ·C2H5  300 - 2500   4.18E-13   2.72   7.63E04      2
  1986TSA/HAM1087   C2H6 + C2H3 → C2H4 + ·C2H5  300 - 2500   1.46E-13   3.30   4.39E04      2
  1986TSA/HAM1087   C2H6 + CH3CO → CH3CHO + ·C2H5  300 - 2500   1.91E-13   2.75   7.33E04      2
  1986TSA/HAM1087   C2H6 + HO2 → ·C2H5 + H2O2  300 - 2500   4.90E-13       6.25E04      2
  1986TSA/HAM1087   C2H6 + ·OH → ·C2H5 + H2O  300 - 2500   5.50E-12   1.04   7591      2
  1986TSA/HAM1087   C2H6 + O2 → ·C2H5 + HO2  300 - 2500   6.71E-11       2.13E05      2
  1986TSA/HAM1087   C2H6 + H· → H2 + ·C2H5  300 - 2500   4.20E-13   3.50   2.16E04      2
  1986TSA/HAM1087   C2H6 + O· → ·C2H5 + ·OH  300 - 2500   6.09E-11   0.60   3.06E04      2
  1986TSA/HAM1087   C2H6 + ·CH2 → Products  300 - 2500   <3.01E-19              2
  1986TSA/HAM1087   C2H4 → C2H2 + H2  1200 - 2500   9.75E13   0.44   3.72E05      1
  1986TSA/HAM1087   C2H4 + C2H4 → ·C2H5 + C2H3  300 - 2500   8.00E-10       2.99E05      2
  1986TSA/HAM1087   C2H4 + C2H2 → C2H3 + C2H3  300 - 2500   4.00E-11       2.86E05      2
  1986TSA/HAM1087   C2H4 + CO → HCO + C2H3  300 - 2500   2.51E-10       3.79E05      2
  1986TSA/HAM1087   C2H4 + H2 → ·C2H5 + H·  300 - 2500   1.69E-11       2.85E05      2
  1986TSA/HAM1087   C2H4 + ·C2H → Vinylacetylene + H·  300 - 2500   2.01E-11              2
  1986TSA/HAM1087   C2H4 + CH3O· → Products  300 - 2500   2.01E-13       2.83E04      2
  1986TSA/HAM1087   C2H4 + ·CH3 → CH4 + C2H3  300 - 2500   1.57E-14   3.70   3.97E04      2
  1986TSA/HAM1087   C2H4 + ·CH3 → 1-C3H7  300 - 2500   5.50E-13       3.23E04      2
  1986TSA/HAM1087   C2H4 + C2H3 → 1,3-Butadiene + H·  300 - 2500   8.30E-13       3.06E04      2
  1986TSA/HAM1087   C2H4 + HO2 → CH3CHO + ·OH  300 - 2500   1.00E-14       3.33E04      2
  1986TSA/HAM1087   C2H4 + ·OH → C2H3 + H2O  300 - 2500   1.66E-13   2.75   1.75E04      2
  1986TSA/HAM1087   C2H4 + ·OH → HOCH2CH2·  300 - 1500   9.00E-12              2
  1986TSA/HAM1087   C2H4 + O2 → C2H3 + HO2  300 - 2500   7.01E-11       2.41E05      2
  1986TSA/HAM1087   C2H4 + H· → H2 + C2H3  300 - 2500   4.00E-12   2.53   5.12E04      2
  1986TSA/HAM1087   C2H4 + H· → ·C2H5  300 - 2500   6.79E-12   1.49   4149      2
  1986TSA/HAM1087   C2H4 + ·C2H5 → C2H6 + C2H3  300 - 2500   5.83E-14   3.13   7.53E04      2
  1986TSA/HAM1087   C2H4 + O· → ·CH3 + HCO  300 - 2500   1.50E-12   1.55   1788      2
  1986TSA/HAM1087   C2H4 + ·CH2 → Products  300 - 2500   <3.01E-14              2
  1986TSA/HAM1087   C2H2 → ·C2H + H·  700 - 2500   2.63E15       5.19E05      1
  1986TSA/HAM1087   C2H2 + C2H2 → ·C2H + C2H3  300 - 2500   1.60E-11       3.53E05      2
  1986TSA/HAM1087   C2H2 + CO → ·C2H + HCO  300 - 2500   8.00E-10       4.46E05      2
  1986TSA/HAM1087   C2H2 + H2 → C2H4  300 - 2500   5.00E-13       1.63E05      2
  1986TSA/HAM1087   C2H2 + H2 → C2H3 + H·  300 - 2500   4.00E-12       2.72E05      2
  1986TSA/HAM1087   C2H2 + ·C2H → 1,3-Butadiyne + H·  300 - 2500   4.00E-11              2
  1986TSA/HAM1087   C2H2 + CH3O· → Products  300 - 2500   2.01E-13       8.31E04      2
  1986TSA/HAM1087   C2H2 + ·CH3 → CH4 + ·C2H  300 - 2500   3.01E-13       7.23E04      2
  1986TSA/HAM1087   C2H2 + ·CH3 → ·CH2CH=CH2  300 - 2500   1.00E-12       3.23E04      2
  1986TSA/HAM1087   C2H2 + HO2 → H2C=C=O + ·OH  300 - 2500   1.00E-14       3.33E04      2
  1986TSA/HAM1087   C2H2 + ·OH → ·C2H + H2O  300 - 2500   1.03E-13   2.68   5.04E04      2
  1986TSA/HAM1087   C2H2 + O2 → ·C2H + HO2  300 - 2500   2.01E-11       3.12E05      2
  1986TSA/HAM1087   C2H2 + H· → H2 + ·C2H  300 - 2500   1.00E-10       9.31E04      2
  1986TSA/HAM1087   C2H2 + H· → C2H3  700 - 2500   1.08E-25   -7.27   3.02E04      3
  1986TSA/HAM1087   C2H2 + ·C2H5 → C2H6 + ·C2H  300 - 2500   4.50E-13       9.81E04      2
  1986TSA/HAM1087   C2H2 + O· → Products  300 - 2500   2.91E-11       1.33E04      2
  1986TSA/HAM1087   C2H2 + O· → H· + HCCO  300 - 2500   1.50E-11       1.90E04      2
  1986TSA/HAM1087   C2H2 + ·CH2 → Products  300 - 2500   5.80E-12              2
  1986TSA/HAM1087   CO2 + H· → CO + ·OH  300 - 2500   2.51E-10       1.11E05      2
  1986TSA/HAM1087   CO2 + O· → CO + O2  300 - 2500   2.81E-11       2.20E05      2
  1986TSA/HAM1087   CO2 + ·CH2 → CH2O + CO  300 - 2500   3.90E-14              2
  1986TSA/HAM1087   CO + CH3O· → CO2 + ·CH3  300 - 2500   2.61E-11       4.94E04      2
  1986TSA/HAM1087   CO + ·CH3 → CH3CO  300 - 1700   7.83E-29   -7.56   4.56E04      3
  1986TSA/HAM1087   CO + C2H3 → CH2=CHC(·)O  300 - 2500   2.51E-13       2.01E04      2
  1986TSA/HAM1087   CO + HO2 → CO2 + ·OH  300 - 2500   2.51E-10       9.89E04      2
  1986TSA/HAM1087   CO + O2 → CO2 + O·  300 - 2500   4.20E-12       2.00E05      2
  1986TSA/HAM1087   CO + H· → HCO  800 - 2500   5.46E-32   -1.82   1.55E04      3
  1986TSA/HAM1087   CO + ·C2H5 → CH3CH2C(O)·  300 - 2500   2.51E-13       2.01E04      2
  1986TSA/HAM1087   CO + O· → CO2  300 - 2500   1.70E-33       1.26E04      3
  1986TSA/HAM1087   CO + ·CH2 → H2C=C=O  300 - 2500   <1.00E-15              2
  1986TSA/HAM1087   H2 → H· + H·  600 - 2000   2.61E-08   -1.40   4.37E05      2
  1986TSA/HAM1087   H2 + ·C2H → C2H2 + H·  250 - 300   1.91E-11       1.21E04   1.47E-13  2
  1986TSA/HAM1087   H2 + CH3O2· → CH3OOH + H·  300 - 2500   5.00E-11       1.09E05      2
  1986TSA/HAM1087   H2 + ·CH3 → CH4 + H·  300 - 2500   2.52E-14   3.12   3.64E04      2
  1986TSA/HAM1087   H2 + HCO → CH2O + H·  300 - 2500   2.66E-13   2.00   7.46E04      2
  1986TSA/HAM1087   H2 + C2H3 → C2H4 + H·  300 - 2500   1.61E-13   2.63   3.58E04      2
  1986TSA/HAM1087   H2 + CH3CO → CH3CHO + H·  300 - 2500   2.18E-13   1.82   7.37E04      2
  1986TSA/HAM1087   H2 + HO2 → H2O2 + H·  300 - 2500   5.00E-11       1.09E05      2
  1986TSA/HAM1087   H2 + ·OH →