Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Curran, H.J.
Title:   Rate constant estimation for C-1 to C-4 alkyl and alkoxyl radical decomposition
Journal:   Int. J. Chem. Kinet.
Volume:   38
Page(s):   250 - 275
Year:   2006
Reference type:   Journal article
Squib:   2006CUR250-275

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2006CUR250-275   C2H4 + ·C2H5  298 - 2000   1.25E-11   1.07   6067   1.08E-12  2
  2006CUR250-275   CH3CH=CH2 + 2-C3H7  298 - 2000   1.29E-11   0.51   5146   1.61E-12  2
  2006CUR250-275   CH3CH=CH2 + 1-C3H7  298 - 2000   7.59E-12   0.51   1.10E04   9.09E-14  2
  2006CUR250-275   Isobutene + tert-C4H9  298 - 2000   3.22E-11   0.51   5146   4.03E-12  2
  2006CUR250-275   Isobutene + iso-C4H9  298 - 2000   1.90E-11   0.51   1.10E04   2.27E-13  2
  2006CUR250-275   1-C4H8 + 1-C4H9  298 - 2000   7.59E-12   0.51   1.10E04   9.09E-14  2
  2006CUR250-275   C2H4 + ·CH31-C3H7  298 - 2000   4.00E-14   2.48   2.56E04   1.28E-18  2
  2006CUR250-275   CH3CH=CH2 + ·CH3sec-C4H9  298 - 2000   4.00E-14   2.48   2.56E04   1.28E-18  2
  2006CUR250-275   Isobutene + ·CH3(CH3)2C(·)CH2CH3  298 - 2000   4.00E-14   2.48   2.56E04   1.28E-18  2
  2006CUR250-275   Isobutene + ·CH3Neopentyl  298 - 2000   2.95E-15   2.48   3.56E04   1.67E-21  2
  2006CUR250-275   CH3CH=CH2 + ·CH3iso-C4H9  298 - 2000   1.27E-14   2.67   2.87E04   1.20E-19  2
  2006CUR250-275   CH3CH=CH2 + ·C2H5CH3CH2CH2CH(·)CH3  298 - 2000   2.00E-14   2.48   2.56E04   6.39E-19  2
  2006CUR250-275   C2H4 + ·C2H51-C4H9  298 - 2000   3.00E-14   2.48   2.56E04   9.58E-19  2
  2006CUR250-275   ·C2H5C2H4 +   298 - 2000   6.86E12   0.95   1.55E05   5.56E-15  1
  2006CUR250-275   2-C3H7CH3CH=CH2 +   298 - 2000   1.71E13   0.48   1.54E05   1.85E-14  1
  2006CUR250-275   1-C3H7CH3CH=CH2 +   298 - 2000   1.09E13   0.17   1.49E05   8.22E-14  1
  2006CUR250-275   1-C3H7C2H4 + ·CH3  298 - 2000   1.31E13   0.87   1.27E05   6.02E-10  1
  2006CUR250-275   tert-C4H9Isobutene +   298 - 2000   3.05E13   0.70   1.53E05   4.63E-14  1
  2006CUR250-275   iso-C4H9Isobutene +   298 - 2000   3.39E13   0.12   1.41E05   6.76E-12  1
  2006CUR250-275   1-C4H91-C4H8 +   298 - 2000   1.10E13   0.25   1.49E05   7.13E-14  1
  2006CUR250-275   sec-C4H91-C4H8 +   298 - 2000   8.62E12   0.59   1.54E05   8.56E-15  1
  2006CUR250-275   sec-C4H9CH3CH=CHCH3 +   298 - 2000   1.98E12   0.34   1.49E05   1.76E-14  1
  2006CUR250-275   1-C4H9C2H4 + ·C2H5  298 - 2000   4.92E13   0.46   1.23E05   1.18E-08  1
  2006CUR250-275   iso-C4H9CH3CH=CH2 + ·CH3  298 - 2000   7.71E13   0.77   1.28E05   2.32E-09  1
  2006CUR250-275   sec-C4H9CH3CH=CH2 + ·CH3  298 - 2000   1.79E13   1.04   1.27E05   9.73E-10  1
  2006CUR250-275   NeopentylIsobutene + ·CH3  298 - 2000   7.62E14   -1.11   1.38E05   5.22E-10  1
  2006CUR250-275   (CH3)2C(·)CH2CH3Isobutene + ·CH3  298 - 2000   2.33E13   1.19   1.27E05   1.52E-09  1
  2006CUR250-275   CH3CH2CH2CH(·)CH3CH3CH=CH2 + ·C2H5  298 - 2000   4.68E13   0.64   1.23E05   1.35E-08  1
  2006CUR250-275   CH2O + CH3  298 - 2000   3.99E-11       1.72E04   3.86E-14  2
  2006CUR250-275   CH3CHO + CH3CH2  298 - 2000   1.33E-11       2.68E04   2.69E-16  2
  2006CUR250-275   C2H5CHO + n-C3H7O  298 - 2000   6.64E-12       2.62E04   1.70E-16  2
  2006CUR250-275   Acetone + (CH3)2CHO·  298 - 2000   3.32E-12       3.04E04   1.55E-17  2
  2006CUR250-275   CH2O + ·CH3CH3CH2  298 - 2000   4.98E-13       2.65E04   1.12E-17  2
  2006CUR250-275   CH2O + ·C2H5n-C3H7O  298 - 2000   1.66E-13       1.46E04   4.53E-16  2
  2006CUR250-275   CH2O + 1-C3H7CH3CH2CH2CH2  298 - 2000   8.30E-14       1.45E04   2.42E-16  2
  2006CUR250-275   CH2O + 2-C3H7 → (CH3)2CHCH2  298 - 2000   8.30E-14       9749   1.62E-15  2
  2006CUR250-275   CH3CHO + ·CH3(CH3)2CHO·  298 - 2000   1.66E-13       3.87E04   2.70E-20  2
  2006CUR250-275   CH3CHO + ·C2H5 → CH3CH2CH(CH3)O·  298 - 2000   5.53E-14       2.68E04   1.13E-18  2
  2006CUR250-275   C2H5CHO + ·CH3 → CH3CH2CH(CH3)O·  298 - 2000   8.30E-14       3.78E04   1.94E-20  2
  2006CUR250-275   Acetone + ·CH3 → (CH3)3CO·  298 - 2000   4.15E-14       4.22E04   1.65E-21  2
  2006CUR250-275   CH3CH2O +   298 - 2000   1.69E14   -0.39   1.10E05   7.36E-06  1
  2006CUR250-275   CH3CH2CH3CHO +   298 - 2000   1.07E14   -0.69   9.30E04   5.31E-03  1
  2006CUR250-275   CH3CH2CH2O + ·CH3  298 - 2000   1.33E15   -2.02   8.68E04   0.80  1
  2006CUR250-275   n-C3H7OC2H5CHO +   298 - 2000   6.38E12   0.75   8.81E04   2.29E-03  1
  2006CUR250-275   n-C3H7OCH2O + ·C2H5  298 - 2000   2.36E15   -2.45   7.10E04   846  1
  2006CUR250-275   (CH3)2CHO·Acetone +   298 - 2000   5.62E13   -0.48   8.40E04   0.11  1
  2006CUR250-275   (CH3)2CHO·CH3CHO + ·CH3  298 - 2000   3.32E15   -1.70   7.17E04   892  1
  2006CUR250-275   CH3CH2CH2CH2CH2O + 1-C3H7  298 - 2000   1.44E15   -2.44   7.05E04   644  1
  2006CUR250-275   CH3CH2CH(CH3)O· → CH3CHO + ·C2H5  298 - 2000   8.17E15   -2.76   5.85E04   4.57E05  1
  2006CUR250-275   CH3CH2CH(CH3)O· → C2H5CHO + ·CH3  298 - 2000   2.75E14   -0.89   6.92E04   207  1
  2006CUR250-275   (CH3)3CO· → Acetone + ·CH3  298 - 2000   7.80E15   -2.55   7.05E04   3485  1
  2006CUR250-275   (CH3)2CHCH2O· → CH2O + 2-C3H7  298 - 2000   6.31E15   -2.80   6.38E04   4.20E04  1

Search returned 52 records.